β-Si-H agostic rigidity in a solvent-free indenyl-derived ansa-yttrocene silylamide

Wolfgang A. Herrmann; Jörg Eppinger; Michael Spiegler; Oliver Runte; Reiner Anwander

doi:10.1021/om9608925

β-Si-H agostic rigidity in a solvent-free indenyl-derived ansa-yttrocene silylamide

Wolfgang A. Herrmann, Jörg Eppinger, Michael Spiegler, Oliver Runte, Reiner Anwander^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

116 Scopus citations

Abstract

The novel ansa-yttrocene complex [(η⁵-C₉H₅-2-Me)₂SiMe ₂]Y[N(SiHMe₂)₂], derived from a linked bis-(indenyl) ligand, has been prepared by an amine elimination reaction. Utilization of Y[N(SiHMe₂)₂]₃(THF)₂ as a sterically flexible amide precursor ensures a high-yield synthesis, favorable solubility behavior, and the formation of two β-Si-H agostically fused metallacycles.

Original language	English (US)
Pages (from-to)	1813-1815
Number of pages	3
Journal	Organometallics
Volume	16
Issue number	9
DOIs	https://doi.org/10.1021/om9608925
State	Published - Apr 29 1997
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om9608925

Cite this

@article{ed739716e3ad4a999279b3b025e42350,

title = "β-Si-H agostic rigidity in a solvent-free indenyl-derived ansa-yttrocene silylamide",

abstract = "The novel ansa-yttrocene complex [(η5-C9H5-2-Me)2SiMe 2]Y[N(SiHMe2)2], derived from a linked bis-(indenyl) ligand, has been prepared by an amine elimination reaction. Utilization of Y[N(SiHMe2)2]3(THF)2 as a sterically flexible amide precursor ensures a high-yield synthesis, favorable solubility behavior, and the formation of two β-Si-H agostically fused metallacycles.",

author = "Herrmann, {Wolfgang A.} and J{\"o}rg Eppinger and Michael Spiegler and Oliver Runte and Reiner Anwander",

year = "1997",

month = apr,

day = "29",

doi = "10.1021/om9608925",

language = "English (US)",

volume = "16",

pages = "1813--1815",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - β-Si-H agostic rigidity in a solvent-free indenyl-derived ansa-yttrocene silylamide

AU - Herrmann, Wolfgang A.

AU - Eppinger, Jörg

AU - Spiegler, Michael

AU - Runte, Oliver

AU - Anwander, Reiner

PY - 1997/4/29

Y1 - 1997/4/29

N2 - The novel ansa-yttrocene complex [(η5-C9H5-2-Me)2SiMe 2]Y[N(SiHMe2)2], derived from a linked bis-(indenyl) ligand, has been prepared by an amine elimination reaction. Utilization of Y[N(SiHMe2)2]3(THF)2 as a sterically flexible amide precursor ensures a high-yield synthesis, favorable solubility behavior, and the formation of two β-Si-H agostically fused metallacycles.

AB - The novel ansa-yttrocene complex [(η5-C9H5-2-Me)2SiMe 2]Y[N(SiHMe2)2], derived from a linked bis-(indenyl) ligand, has been prepared by an amine elimination reaction. Utilization of Y[N(SiHMe2)2]3(THF)2 as a sterically flexible amide precursor ensures a high-yield synthesis, favorable solubility behavior, and the formation of two β-Si-H agostically fused metallacycles.

UR - http://www.scopus.com/inward/record.url?scp=4043102059&partnerID=8YFLogxK

U2 - 10.1021/om9608925

DO - 10.1021/om9608925

M3 - Article

AN - SCOPUS:4043102059

SN - 0276-7333

VL - 16

SP - 1813

EP - 1815

JO - Organometallics

JF - Organometallics

IS - 9

ER -

β-Si-H agostic rigidity in a solvent-free indenyl-derived ansa-yttrocene silylamide

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this