η6-Arene complexes of ruthenium and osmium with pendant donor functionalities

Thomas Reiner; Markus Waibel; Alexander N. Marziale; Dominik Jantke; Florian J. Kiefer; Thomas F. Fässler; Jörg Eppinger

doi:10.1016/j.jorganchem.2010.08.008

η6-Arene complexes of ruthenium and osmium with pendant donor functionalities

Thomas Reiner, Markus Waibel, Alexander N. Marziale, Dominik Jantke, Florian J. Kiefer, Thomas F. Fässler, Jörg Eppinger

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Conversion of 4′-(2,5-dihydrophenyl)butanol or N-trifluoroacetyl-2,5- dihydrobenzylamine with MCl3·n H2O (M = Ru, Os) affords the corresponding dimeric η6-arene complexes in good to excellent yields. Under similar reaction conditions, the amine functionalized arene precursor 2,5-dihydrobenzylamine yields the corresponding Ru(II) complex. For osmium, HCl induced oxidation leads to formation of [OsCl6] 2- salts. However, under optimized reaction conditions, conversion of the precursor 2,5-dihydrobenzylamine chloride results in clean formation of η6-arene Os(II) complex. X-ray structures of [(η6- benzyl ammonium)(dmso)RuCl2] and (2,5-dihydrobenzyl ammonium) 4[OsCl6]2confirm the spectroscopic data. High stability towards air and acid as well as enhanced solubility in water is observed for all η6-arene complexes. © 2010 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	2667-2672
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	695
Issue number	24
DOIs	https://doi.org/10.1016/j.jorganchem.2010.08.008
State	Published - Nov 2010

ASJC Scopus subject areas

Materials Chemistry
Biochemistry
Organic Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1016/j.jorganchem.2010.08.008

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@article{b453999aacbf4ad7b85371bd6ff7e0c0,

title = "η6-Arene complexes of ruthenium and osmium with pendant donor functionalities",

abstract = "Conversion of 4′-(2,5-dihydrophenyl)butanol or N-trifluoroacetyl-2,5- dihydrobenzylamine with MCl3·n H2O (M = Ru, Os) affords the corresponding dimeric η6-arene complexes in good to excellent yields. Under similar reaction conditions, the amine functionalized arene precursor 2,5-dihydrobenzylamine yields the corresponding Ru(II) complex. For osmium, HCl induced oxidation leads to formation of [OsCl6] 2- salts. However, under optimized reaction conditions, conversion of the precursor 2,5-dihydrobenzylamine chloride results in clean formation of η6-arene Os(II) complex. X-ray structures of [(η6- benzyl ammonium)(dmso)RuCl2] and (2,5-dihydrobenzyl ammonium) 4[OsCl6]2confirm the spectroscopic data. High stability towards air and acid as well as enhanced solubility in water is observed for all η6-arene complexes. {\textcopyright} 2010 Elsevier B.V. All rights reserved.",

author = "Thomas Reiner and Markus Waibel and Marziale, {Alexander N.} and Dominik Jantke and Kiefer, {Florian J.} and F{\"a}ssler, {Thomas F.} and J{\"o}rg Eppinger",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors are grateful to Prof. W. A. Herrmann for generous support. We thank the Stifterverband fur die deutsche Wissenschaft (Projekt-Nr. 11047: ForschungsDozentur MolekulareKatalyse), the Elitenetzwerk Bayern (graduate fellowship for T. R. and A. N. M) andthe IDK NanoCat for funding.",

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language = "English (US)",

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journal = "Journal of Organometallic Chemistry",

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T1 - η6-Arene complexes of ruthenium and osmium with pendant donor functionalities

AU - Reiner, Thomas

AU - Waibel, Markus

AU - Marziale, Alexander N.

AU - Jantke, Dominik

AU - Kiefer, Florian J.

AU - Fässler, Thomas F.

AU - Eppinger, Jörg

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors are grateful to Prof. W. A. Herrmann for generous support. We thank the Stifterverband fur die deutsche Wissenschaft (Projekt-Nr. 11047: ForschungsDozentur MolekulareKatalyse), the Elitenetzwerk Bayern (graduate fellowship for T. R. and A. N. M) andthe IDK NanoCat for funding.

PY - 2010/11

Y1 - 2010/11

N2 - Conversion of 4′-(2,5-dihydrophenyl)butanol or N-trifluoroacetyl-2,5- dihydrobenzylamine with MCl3·n H2O (M = Ru, Os) affords the corresponding dimeric η6-arene complexes in good to excellent yields. Under similar reaction conditions, the amine functionalized arene precursor 2,5-dihydrobenzylamine yields the corresponding Ru(II) complex. For osmium, HCl induced oxidation leads to formation of [OsCl6] 2- salts. However, under optimized reaction conditions, conversion of the precursor 2,5-dihydrobenzylamine chloride results in clean formation of η6-arene Os(II) complex. X-ray structures of [(η6- benzyl ammonium)(dmso)RuCl2] and (2,5-dihydrobenzyl ammonium) 4[OsCl6]2confirm the spectroscopic data. High stability towards air and acid as well as enhanced solubility in water is observed for all η6-arene complexes. © 2010 Elsevier B.V. All rights reserved.

AB - Conversion of 4′-(2,5-dihydrophenyl)butanol or N-trifluoroacetyl-2,5- dihydrobenzylamine with MCl3·n H2O (M = Ru, Os) affords the corresponding dimeric η6-arene complexes in good to excellent yields. Under similar reaction conditions, the amine functionalized arene precursor 2,5-dihydrobenzylamine yields the corresponding Ru(II) complex. For osmium, HCl induced oxidation leads to formation of [OsCl6] 2- salts. However, under optimized reaction conditions, conversion of the precursor 2,5-dihydrobenzylamine chloride results in clean formation of η6-arene Os(II) complex. X-ray structures of [(η6- benzyl ammonium)(dmso)RuCl2] and (2,5-dihydrobenzyl ammonium) 4[OsCl6]2confirm the spectroscopic data. High stability towards air and acid as well as enhanced solubility in water is observed for all η6-arene complexes. © 2010 Elsevier B.V. All rights reserved.

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DO - 10.1016/j.jorganchem.2010.08.008

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VL - 695

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EP - 2672

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 24

ER -

η6-Arene complexes of ruthenium and osmium with pendant donor functionalities

Abstract

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CCDC 713130: Experimental Crystal Structure Determination : bis(2,5-Dihydrobenzylammonium) hexachloro-osmium(iv)

CCDC 713129: Experimental Crystal Structure Determination : (eta^6^-Benzylammonium)-dichloro-(dimethylsulfoxide-S)-ruthenium(ii) chloride

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η6-Arene complexes of ruthenium and osmium with pendant donor functionalities

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 713130: Experimental Crystal Structure Determination : bis(2,5-Dihydrobenzylammonium) hexachloro-osmium(iv)

CCDC 713129: Experimental Crystal Structure Determination : (eta^6^-Benzylammonium)-dichloro-(dimethylsulfoxide-S)-ruthenium(ii) chloride

Cite this