TY - JOUR
T1 - π-Stacked oligo(phenylene vinylene)s based on pseudo-geminal substituted [2.2]paracyclophanes
T2 - Impact of interchain geometry and interactions on the electronic properties
AU - Mukhopadhyay, Sukrit
AU - Jagtap, Subodh P.
AU - Coropceanu, Veaceslav
AU - Brédas, Jean Luc
AU - Collard, David M.
PY - 2012/11/12
Y1 - 2012/11/12
N2 - A clever combination: A series of phenylene vinylene oligomers, in which the conjugated segments are held in a well-defined stacked arrangement along their entire length, was studied experimentally and theoretically (see picture). The impact of the extended interchain interactions on the photophysics of the π-stacked systems is reported.
AB - A clever combination: A series of phenylene vinylene oligomers, in which the conjugated segments are held in a well-defined stacked arrangement along their entire length, was studied experimentally and theoretically (see picture). The impact of the extended interchain interactions on the photophysics of the π-stacked systems is reported.
KW - conjugation
KW - density functional calculations
KW - photophysics
KW - stacking interactions
KW - π interactions
UR - http://www.scopus.com/inward/record.url?scp=84868551240&partnerID=8YFLogxK
U2 - 10.1002/anie.201205738
DO - 10.1002/anie.201205738
M3 - Article
C2 - 23065685
AN - SCOPUS:84868551240
SN - 1433-7851
VL - 51
SP - 11629
EP - 11632
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 46
ER -