1,4-polybutadiene-based particles prepared by aqueous suspension ring-opening metathesis polymerization

Abraham Chemtob; Valérie Héroguez; Yves Gnanou

doi:10.1021/ma049399s

1,4-polybutadiene-based particles prepared by aqueous suspension ring-opening metathesis polymerization

Abraham Chemtob, Valérie Héroguez^*, Yves Gnanou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

This paper describes two different strategies to obtain stable beads of 1,4-polybutadiene (PB) by suspension ring-opening metathesis of 1,5-cyclooctadiene carried out in water. Both rest on the use of amphiphilic stabilizing agents whose hydrophilic/hydrophobic balance was finely tuned. A norbornenyl-ended poly(styrene-b-ethylene oxide) macromonomer and an in situ prepared poly(butadiene-g-ethylene oxide) graft copolymer provided the required stability for PB beads in the range of 20 μm to remain suspended in water.

Original language	English (US)
Pages (from-to)	7619-7627
Number of pages	9
Journal	Macromolecules
Volume	37
Issue number	20
DOIs	https://doi.org/10.1021/ma049399s
State	Published - Oct 5 2004
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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abstract = "This paper describes two different strategies to obtain stable beads of 1,4-polybutadiene (PB) by suspension ring-opening metathesis of 1,5-cyclooctadiene carried out in water. Both rest on the use of amphiphilic stabilizing agents whose hydrophilic/hydrophobic balance was finely tuned. A norbornenyl-ended poly(styrene-b-ethylene oxide) macromonomer and an in situ prepared poly(butadiene-g-ethylene oxide) graft copolymer provided the required stability for PB beads in the range of 20 μm to remain suspended in water.",

author = "Abraham Chemtob and Val{\'e}rie H{\'e}roguez and Yves Gnanou",

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AU - Chemtob, Abraham

AU - Héroguez, Valérie

AU - Gnanou, Yves

PY - 2004/10/5

Y1 - 2004/10/5

N2 - This paper describes two different strategies to obtain stable beads of 1,4-polybutadiene (PB) by suspension ring-opening metathesis of 1,5-cyclooctadiene carried out in water. Both rest on the use of amphiphilic stabilizing agents whose hydrophilic/hydrophobic balance was finely tuned. A norbornenyl-ended poly(styrene-b-ethylene oxide) macromonomer and an in situ prepared poly(butadiene-g-ethylene oxide) graft copolymer provided the required stability for PB beads in the range of 20 μm to remain suspended in water.

AB - This paper describes two different strategies to obtain stable beads of 1,4-polybutadiene (PB) by suspension ring-opening metathesis of 1,5-cyclooctadiene carried out in water. Both rest on the use of amphiphilic stabilizing agents whose hydrophilic/hydrophobic balance was finely tuned. A norbornenyl-ended poly(styrene-b-ethylene oxide) macromonomer and an in situ prepared poly(butadiene-g-ethylene oxide) graft copolymer provided the required stability for PB beads in the range of 20 μm to remain suspended in water.

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JO - Macromolecules

JF - Macromolecules

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ER -

1,4-polybutadiene-based particles prepared by aqueous suspension ring-opening metathesis polymerization

Abstract

ASJC Scopus subject areas

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