TY - JOUR
T1 - 25 years of Reticular Chemistry
AU - Freund, Ralph
AU - Canossa, Stefano
AU - Cohen, Seth M.
AU - Yan, Wei
AU - Deng, Hexiang
AU - Guillerm, Vincent
AU - Eddaoudi, Mohamed
AU - Madden, David G.
AU - Fairen-Jimenez, David
AU - Lyu, Hao
AU - Macreadie, Lauren K.
AU - Ji, Zhe
AU - Zhang, Yuanyuan
AU - Wang, Bo
AU - Haase, Frederik
AU - Wöll, Christof
AU - Zaremba, Orysia
AU - Andreo, Jacopo
AU - Wuttke, Stefan
AU - Diercks, Christian S.
N1 - KAUST Repository Item: Exported on 2021-04-01
PY - 2021/3/29
Y1 - 2021/3/29
N2 - At its core, reticular chemistry has translated the precision and expertise of organic and inorganic synthesis to the solid state. While initial excitement over metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) was undoubtedly fueled by their unprecedented porosity and surface areas, the most profound scientific innovation of the field has been the elaboration of design strategies for the synthesis of extended crystalline solids through strong directional bonds. In this contribution we highlight the different classes of reticular materials that have been developed, how these frameworks can be functionalized and how complexity can be introduced into their backbones. Finally, we show how the structural control over these materials is being extended from the molecular scale to their crystal morphology and shape on the nanoscale, all the way to their shaping on the bulk scale.
AB - At its core, reticular chemistry has translated the precision and expertise of organic and inorganic synthesis to the solid state. While initial excitement over metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) was undoubtedly fueled by their unprecedented porosity and surface areas, the most profound scientific innovation of the field has been the elaboration of design strategies for the synthesis of extended crystalline solids through strong directional bonds. In this contribution we highlight the different classes of reticular materials that have been developed, how these frameworks can be functionalized and how complexity can be introduced into their backbones. Finally, we show how the structural control over these materials is being extended from the molecular scale to their crystal morphology and shape on the nanoscale, all the way to their shaping on the bulk scale.
UR - http://hdl.handle.net/10754/668415
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.202101644
U2 - 10.1002/anie.202101644
DO - 10.1002/anie.202101644
M3 - Article
C2 - 33783111
SN - 1433-7851
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
ER -