2D and 3D silver(I)-ethylenediamine coordination polymers with Ag-Ag argentophilic interactions

Ji Xiang Dai; Hai Liang Zhu; Alexander Rothenberger; Qian Feng Zhang

doi:10.1515/znb-2007-0902

2D and 3D silver(I)-ethylenediamine coordination polymers with Ag-Ag argentophilic interactions

Ji Xiang Dai, Hai Liang Zhu, Alexander Rothenberger, Qian Feng Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Two complexes of silver(I) salts with ethylenediamine (etda) as a ligand were prepared and characterized. The study of the crystal structures (of the 2-hydroxy-4-nitro-benzoate trihydrate (1) and nitrate (2)) has shown that the formation of 2D and 3D coordination polymer networks results from etda ligands bridging the silver atoms which are connected via Ag-Ag argentophilic interactions.

Original language	English (US)
Pages (from-to)	1112-1116
Number of pages	5
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	62
Issue number	9
DOIs	https://doi.org/10.1515/znb-2007-0902
State	Published - Sep 2007
Externally published	Yes

Keywords

Ag-ag interaction
Coordination polymer
Crystal structure
Ethylenediamine
Silver compound

ASJC Scopus subject areas

General Chemistry

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title = "2D and 3D silver(I)-ethylenediamine coordination polymers with Ag-Ag argentophilic interactions",

abstract = "Two complexes of silver(I) salts with ethylenediamine (etda) as a ligand were prepared and characterized. The study of the crystal structures (of the 2-hydroxy-4-nitro-benzoate trihydrate (1) and nitrate (2)) has shown that the formation of 2D and 3D coordination polymer networks results from etda ligands bridging the silver atoms which are connected via Ag-Ag argentophilic interactions.",

keywords = "Ag-ag interaction, Coordination polymer, Crystal structure, Ethylenediamine, Silver compound",

author = "Dai, {Ji Xiang} and Zhu, {Hai Liang} and Alexander Rothenberger and Zhang, {Qian Feng}",

note = "Funding Information: This work was supported by the Science and Technological Fund of Anhui Province for Outstanding Youth (06046100) and the Research Fund for the Returned Overseas Talents of Anhui Province (2006Z041).",

year = "2007",

month = sep,

doi = "10.1515/znb-2007-0902",

language = "English (US)",

volume = "62",

pages = "1112--1116",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

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T1 - 2D and 3D silver(I)-ethylenediamine coordination polymers with Ag-Ag argentophilic interactions

AU - Dai, Ji Xiang

AU - Zhu, Hai Liang

AU - Rothenberger, Alexander

AU - Zhang, Qian Feng

N1 - Funding Information: This work was supported by the Science and Technological Fund of Anhui Province for Outstanding Youth (06046100) and the Research Fund for the Returned Overseas Talents of Anhui Province (2006Z041).

PY - 2007/9

Y1 - 2007/9

N2 - Two complexes of silver(I) salts with ethylenediamine (etda) as a ligand were prepared and characterized. The study of the crystal structures (of the 2-hydroxy-4-nitro-benzoate trihydrate (1) and nitrate (2)) has shown that the formation of 2D and 3D coordination polymer networks results from etda ligands bridging the silver atoms which are connected via Ag-Ag argentophilic interactions.

AB - Two complexes of silver(I) salts with ethylenediamine (etda) as a ligand were prepared and characterized. The study of the crystal structures (of the 2-hydroxy-4-nitro-benzoate trihydrate (1) and nitrate (2)) has shown that the formation of 2D and 3D coordination polymer networks results from etda ligands bridging the silver atoms which are connected via Ag-Ag argentophilic interactions.

KW - Ag-ag interaction

KW - Coordination polymer

KW - Crystal structure

KW - Ethylenediamine

KW - Silver compound

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U2 - 10.1515/znb-2007-0902

DO - 10.1515/znb-2007-0902

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SN - 0932-0776

VL - 62

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EP - 1116

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 9

ER -

2D and 3D silver(I)-ethylenediamine coordination polymers with Ag-Ag argentophilic interactions

Abstract

Keywords

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