(2S)-3-(4-Amino-3-nitrophenyl)-2-(9H-fluoren-9-ylmethoxycarbonylamino) propanoic acid dichloromethane disolvate

Piotr Stefanowicz; Łukasz Jaremko; Mariusz Jaremko; Anna Staszewska; Zbigniew Szewczuk; Iwona Bryndal; Tadeusz Lis

doi:10.1107/S1600536806028273

(2S)-3-(4-Amino-3-nitrophenyl)-2-(9H-fluoren-9-ylmethoxycarbonylamino) propanoic acid dichloromethane disolvate

Piotr Stefanowicz, Łukasz Jaremko, Mariusz Jaremko, Anna Staszewska, Zbigniew Szewczuk, Iwona Bryndal^*, Tadeusz Lis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, C₂₄H₂₁N₃O ₆·2CH₂Cl₂, crystallizes with two independent molecules in the asymmetric unit, each with a different conformation. In the crystal structure, molecules form two-dimensional sheets in the ab plane due to a combination of O-H⋯O and N-H⋯O hydrogen bonds. Only edge-to-face stacking interactions are observed between fluorenyl aromatic groups of adjacent sheets. Solvent molecules are located within the intermolecular voids along the b axis and fill the spaces between carbamate linkages or lie between the fluorenyl aromatic groups.

Original language	English (US)
Pages (from-to)	o3555-o3557
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	62
Issue number	8
DOIs	https://doi.org/10.1107/S1600536806028273
State	Published - Aug 2006
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "(2S)-3-(4-Amino-3-nitrophenyl)-2-(9H-fluoren-9-ylmethoxycarbonylamino) propanoic acid dichloromethane disolvate",

abstract = "The title compound, C24H21N3O 6·2CH2Cl2, crystallizes with two independent molecules in the asymmetric unit, each with a different conformation. In the crystal structure, molecules form two-dimensional sheets in the ab plane due to a combination of O-H⋯O and N-H⋯O hydrogen bonds. Only edge-to-face stacking interactions are observed between fluorenyl aromatic groups of adjacent sheets. Solvent molecules are located within the intermolecular voids along the b axis and fill the spaces between carbamate linkages or lie between the fluorenyl aromatic groups.",

author = "Piotr Stefanowicz and {\L}ukasz Jaremko and Mariusz Jaremko and Anna Staszewska and Zbigniew Szewczuk and Iwona Bryndal and Tadeusz Lis",

year = "2006",

month = aug,

doi = "10.1107/S1600536806028273",

language = "English (US)",

volume = "62",

pages = "o3555--o3557",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - (2S)-3-(4-Amino-3-nitrophenyl)-2-(9H-fluoren-9-ylmethoxycarbonylamino) propanoic acid dichloromethane disolvate

AU - Stefanowicz, Piotr

AU - Jaremko, Łukasz

AU - Jaremko, Mariusz

AU - Staszewska, Anna

AU - Szewczuk, Zbigniew

AU - Bryndal, Iwona

AU - Lis, Tadeusz

PY - 2006/8

Y1 - 2006/8

N2 - The title compound, C24H21N3O 6·2CH2Cl2, crystallizes with two independent molecules in the asymmetric unit, each with a different conformation. In the crystal structure, molecules form two-dimensional sheets in the ab plane due to a combination of O-H⋯O and N-H⋯O hydrogen bonds. Only edge-to-face stacking interactions are observed between fluorenyl aromatic groups of adjacent sheets. Solvent molecules are located within the intermolecular voids along the b axis and fill the spaces between carbamate linkages or lie between the fluorenyl aromatic groups.

AB - The title compound, C24H21N3O 6·2CH2Cl2, crystallizes with two independent molecules in the asymmetric unit, each with a different conformation. In the crystal structure, molecules form two-dimensional sheets in the ab plane due to a combination of O-H⋯O and N-H⋯O hydrogen bonds. Only edge-to-face stacking interactions are observed between fluorenyl aromatic groups of adjacent sheets. Solvent molecules are located within the intermolecular voids along the b axis and fill the spaces between carbamate linkages or lie between the fluorenyl aromatic groups.

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U2 - 10.1107/S1600536806028273

DO - 10.1107/S1600536806028273

M3 - Article

AN - SCOPUS:33747195011

SN - 1600-5368

VL - 62

SP - o3555-o3557

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

(2S)-3-(4-Amino-3-nitrophenyl)-2-(9H-fluoren-9-ylmethoxycarbonylamino) propanoic acid dichloromethane disolvate

Abstract

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