4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagomé lattice and the M6L 12 octahedron

Yunling Liu; Victor Ch Kravtsov; Derek A. Beauchamp; Jarrod F. Eubank; Mohamed Eddaoudi

doi:10.1021/ja051259q

4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagomé lattice and the M₆L ₁₂ octahedron

Yunling Liu, Victor Ch Kravtsov, Derek A. Beauchamp, Jarrod F. Eubank, Mohamed Eddaoudi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

171 Scopus citations

Abstract

Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO₃)₃·2H₂O and 2,5-pyridinedicarboxylic acid (2,5-H₂PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M₆L₁₂ discrete octahedron.

Original language	English (US)
Pages (from-to)	7266-7267
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	20
DOIs	https://doi.org/10.1021/ja051259q
State	Published - May 25 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja051259q

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title = "4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagom{\'e} lattice and the M6L 12 octahedron",

abstract = "Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3·2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagom{\'e} lattice and an unprecedented M6L12 discrete octahedron.",

author = "Yunling Liu and Kravtsov, {Victor Ch} and Beauchamp, {Derek A.} and Eubank, {Jarrod F.} and Mohamed Eddaoudi",

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AU - Beauchamp, Derek A.

AU - Eubank, Jarrod F.

AU - Eddaoudi, Mohamed

PY - 2005/5/25

Y1 - 2005/5/25

N2 - Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3·2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron.

AB - Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3·2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron.

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U2 - 10.1021/ja051259q

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4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagomé lattice and the M₆L ₁₂ octahedron

Abstract

ASJC Scopus subject areas

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