A facile metal-free "grafting-from" route from acrylamide-based substrate toward complex macromolecular combs

Junpeng Zhao; Haleema Alamri; Nikos Hadjichristidis

doi:10.1039/c3cc44131h

A facile metal-free "grafting-from" route from acrylamide-based substrate toward complex macromolecular combs

Junpeng Zhao, Haleema Alamri, Nikos Hadjichristidis

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

High-molecular-weight poly(N,N-dimethylacrylamide-co-acrylamide) was used as a model functional substrate to investigate phosphazene base (t-BuP 4)-promoted metal-free anionic graft polymerization utilizing primary amide moieties as initiating sites. The (co)polymerization of epoxides was proven to be effective, leading to macromolecular combs with side chains being single- or double-graft homopolymer, block copolymer and statistical copolymer. © 2013 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	7079
Journal	Chemical Communications
Volume	49
Issue number	63
DOIs	https://doi.org/10.1039/c3cc44131h
State	Published - 2013

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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10.1039/c3cc44131h

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abstract = "High-molecular-weight poly(N,N-dimethylacrylamide-co-acrylamide) was used as a model functional substrate to investigate phosphazene base (t-BuP 4)-promoted metal-free anionic graft polymerization utilizing primary amide moieties as initiating sites. The (co)polymerization of epoxides was proven to be effective, leading to macromolecular combs with side chains being single- or double-graft homopolymer, block copolymer and statistical copolymer. {\textcopyright} 2013 The Royal Society of Chemistry.",

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N1 - KAUST Repository Item: Exported on 2020-10-01

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AB - High-molecular-weight poly(N,N-dimethylacrylamide-co-acrylamide) was used as a model functional substrate to investigate phosphazene base (t-BuP 4)-promoted metal-free anionic graft polymerization utilizing primary amide moieties as initiating sites. The (co)polymerization of epoxides was proven to be effective, leading to macromolecular combs with side chains being single- or double-graft homopolymer, block copolymer and statistical copolymer. © 2013 The Royal Society of Chemistry.

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JO - Chemical Communications

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A facile metal-free "grafting-from" route from acrylamide-based substrate toward complex macromolecular combs

Abstract

ASJC Scopus subject areas

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