A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis

Anastasiya Bavykina; Alma Itzel Olivos Suarez; Dmitrii Osadchii; Rahul Valecha; Robert Franz; Michiel Makkee; Freek Kapteijn; Jorge Gascon

doi:10.1021/acsami.7b07339

A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis

Anastasiya Bavykina, Alma Itzel Olivos Suarez, Dmitrii Osadchii, Rahul Valecha, Robert Franz, Michiel Makkee, Freek Kapteijn, Jorge Gascon

Research output: Contribution to journal › Article › peer-review

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Abstract

A quasi Chemical Vapour Deposition method for the manufacturing of well-defined Covalent Triazine Framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilisation of two different homogeneous catalysts: 1) an IrIIICp*-based catalyst for the hydrogen production from formic acid, and 2) a PtII-based for the direct activation of methane via Periana chemistry. The immobilised catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF based catalysts can be further optimised by engineering at different length-scales.

Original language	English (US)
Pages (from-to)	26060-26065
Number of pages	6
Journal	ACS Applied Materials & Interfaces
Volume	9
Issue number	31
DOIs	https://doi.org/10.1021/acsami.7b07339
State	Published - Jul 30 2017

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10.1021/acsami.7b07339

https://repository.kaust.edu.sa/bitstream/10754/625243/1/acsami.7b07339.pdf

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title = "A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis",

abstract = "A quasi Chemical Vapour Deposition method for the manufacturing of well-defined Covalent Triazine Framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilisation of two different homogeneous catalysts: 1) an IrIIICp*-based catalyst for the hydrogen production from formic acid, and 2) a PtII-based for the direct activation of methane via Periana chemistry. The immobilised catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF based catalysts can be further optimised by engineering at different length-scales.",

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AU - Bavykina, Anastasiya

AU - Olivos Suarez, Alma Itzel

AU - Osadchii, Dmitrii

AU - Valecha, Rahul

AU - Franz, Robert

AU - Makkee, Michiel

AU - Kapteijn, Freek

AU - Gascon, Jorge

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2017/7/30

Y1 - 2017/7/30

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AB - A quasi Chemical Vapour Deposition method for the manufacturing of well-defined Covalent Triazine Framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilisation of two different homogeneous catalysts: 1) an IrIIICp*-based catalyst for the hydrogen production from formic acid, and 2) a PtII-based for the direct activation of methane via Periana chemistry. The immobilised catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF based catalysts can be further optimised by engineering at different length-scales.

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JO - ACS Applied Materials & Interfaces

JF - ACS Applied Materials & Interfaces

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A facile method for the preparation of Covalent Triazine Framework coated monoliths as catalyst support - applications in C1 catalysis

Abstract

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