A generalized kinetic model for the partial oxidation of n-butane to maleic anhydride under aerobic and anaerobic conditions

Jorge Gascon Sabate; R. Valenciano; C. Téllez; J. Herguido; M. Menéndez

doi:10.1016/j.ces.2006.05.023

A generalized kinetic model for the partial oxidation of n-butane to maleic anhydride under aerobic and anaerobic conditions

Jorge Gascon Sabate, R. Valenciano, C. Téllez, J. Herguido, M. Menéndez^*

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The kinetics of n-butane oxidation for the production of maleic anhydride (MA) over a commercial VPO catalyst has been investigated under aerobic and anaerobic conditions and at a temperature range of 400-435 ^{{ring operator}} C. A kinetic model that can be applied under both aerobic and anaerobic conditions is presented. The model considers three types of oxygen: adsorbed oxygen, surface lattice oxygen and sub-surface lattice oxygen. Both adsorbed and surface lattice oxygen are considered active for the production of maleic anhydride and CO_x.

Original language	English (US)
Pages (from-to)	6385-6394
Number of pages	10
Journal	CHEMICAL ENGINEERING SCIENCE
Volume	61
Issue number	19
DOIs	https://doi.org/10.1016/j.ces.2006.05.023
State	Published - Oct 2006

Keywords

Kinetics
Maleic anhydride
Oxidation
Partial oxidation
VPO catalyst
n-butane

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering

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10.1016/j.ces.2006.05.023

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title = "A generalized kinetic model for the partial oxidation of n-butane to maleic anhydride under aerobic and anaerobic conditions",

abstract = "The kinetics of n-butane oxidation for the production of maleic anhydride (MA) over a commercial VPO catalyst has been investigated under aerobic and anaerobic conditions and at a temperature range of 400-435 {ring operator} C. A kinetic model that can be applied under both aerobic and anaerobic conditions is presented. The model considers three types of oxygen: adsorbed oxygen, surface lattice oxygen and sub-surface lattice oxygen. Both adsorbed and surface lattice oxygen are considered active for the production of maleic anhydride and COx.",

keywords = "Kinetics, Maleic anhydride, Oxidation, Partial oxidation, VPO catalyst, n-butane",

author = "{Gascon Sabate}, Jorge and R. Valenciano and C. T{\'e}llez and J. Herguido and M. Men{\'e}ndez",

year = "2006",

month = oct,

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pages = "6385--6394",

journal = "CHEMICAL ENGINEERING SCIENCE",

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T1 - A generalized kinetic model for the partial oxidation of n-butane to maleic anhydride under aerobic and anaerobic conditions

AU - Gascon Sabate, Jorge

AU - Valenciano, R.

AU - Téllez, C.

AU - Herguido, J.

AU - Menéndez, M.

PY - 2006/10

Y1 - 2006/10

N2 - The kinetics of n-butane oxidation for the production of maleic anhydride (MA) over a commercial VPO catalyst has been investigated under aerobic and anaerobic conditions and at a temperature range of 400-435 {ring operator} C. A kinetic model that can be applied under both aerobic and anaerobic conditions is presented. The model considers three types of oxygen: adsorbed oxygen, surface lattice oxygen and sub-surface lattice oxygen. Both adsorbed and surface lattice oxygen are considered active for the production of maleic anhydride and COx.

AB - The kinetics of n-butane oxidation for the production of maleic anhydride (MA) over a commercial VPO catalyst has been investigated under aerobic and anaerobic conditions and at a temperature range of 400-435 {ring operator} C. A kinetic model that can be applied under both aerobic and anaerobic conditions is presented. The model considers three types of oxygen: adsorbed oxygen, surface lattice oxygen and sub-surface lattice oxygen. Both adsorbed and surface lattice oxygen are considered active for the production of maleic anhydride and COx.

KW - Kinetics

KW - Maleic anhydride

KW - Oxidation

KW - Partial oxidation

KW - VPO catalyst

KW - n-butane

UR - http://www.scopus.com/inward/record.url?scp=33746979152&partnerID=8YFLogxK

U2 - 10.1016/j.ces.2006.05.023

DO - 10.1016/j.ces.2006.05.023

M3 - Article

AN - SCOPUS:33746979152

SN - 0009-2509

VL - 61

SP - 6385

EP - 6394

JO - CHEMICAL ENGINEERING SCIENCE

JF - CHEMICAL ENGINEERING SCIENCE

IS - 19

ER -

A generalized kinetic model for the partial oxidation of n-butane to maleic anhydride under aerobic and anaerobic conditions

Abstract

Keywords

ASJC Scopus subject areas

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