A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope.

Benon P Maliszewski; Ida Ritacco; Marek Beliš; Ishfaq Ibni Hashim; Nikolaos V Tzouras; Lucia Caporaso; Luigi Cavallo; Kristof Van Hecke; Fady Nahra; Catherine S. J. Cazin; Steven P. Nolan

doi:10.1039/d2dt00504b

A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope.

Benon P Maliszewski, Ida Ritacco, Marek Beliš, Ishfaq Ibni Hashim, Nikolaos V Tzouras, Lucia Caporaso, Luigi Cavallo, Kristof Van Hecke, Fady Nahra, Catherine S. J. Cazin, Steven P. Nolan

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9 Scopus citations

Abstract

A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed. The mechanism of this reaction is also elucidated $\textit{via}$ experimental and computational investigations. This straightforward protocol is then used for the synthesis of novel Pt(II)-NHC complexes and its utility is further explored to access key Pt(0)-NHC precatalysts.

Original language	English (US)
Journal	Dalton transactions (Cambridge, England : 2003)
DOIs	https://doi.org/10.1039/d2dt00504b
State	Published - Mar 31 2022

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/d2dt00504b

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@article{1f7d55a1902b4ba9aecde4d52eaad4e7,

title = "A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope.",

abstract = "A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed. The mechanism of this reaction is also elucidated $\textit{via}$ experimental and computational investigations. This straightforward protocol is then used for the synthesis of novel Pt(II)-NHC complexes and its utility is further explored to access key Pt(0)-NHC precatalysts.",

author = "Maliszewski, {Benon P} and Ida Ritacco and Marek Beli{\v s} and Hashim, {Ishfaq Ibni} and Tzouras, {Nikolaos V} and Lucia Caporaso and Luigi Cavallo and {Van Hecke}, Kristof and Fady Nahra and Cazin, {Catherine S. J.} and Nolan, {Steven P.}",

note = "KAUST Repository Item: Exported on 2022-04-05 Acknowledgements: We gratefully acknowledge the VLAIO (SBO project CO2PERATE) and the Special Research Fund (BOF) of Ghent University. Funding of the iBOF project C3 (BOF20/IBF/010) is also gratefully acknowledged. K. V. H., M. B. and C. S. J. C. thank the Research Foundation – Flanders (FWO) for funding. The FWO is also gratefully acknowledged for PhD fellowships to B. P. M (1SB5321N) and N. V. T (11I6921N). Umicore AG and Johnson Matthey are thankfully acknowledged for generous gifts of materials.",

year = "2022",

month = mar,

day = "31",

doi = "10.1039/d2dt00504b",

language = "English (US)",

journal = "Dalton transactions (Cambridge, England : 2003)",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope.

AU - Maliszewski, Benon P

AU - Ritacco, Ida

AU - Beliš, Marek

AU - Hashim, Ishfaq Ibni

AU - Tzouras, Nikolaos V

AU - Caporaso, Lucia

AU - Cavallo, Luigi

AU - Van Hecke, Kristof

AU - Nahra, Fady

AU - Cazin, Catherine S. J.

AU - Nolan, Steven P.

N1 - KAUST Repository Item: Exported on 2022-04-05 Acknowledgements: We gratefully acknowledge the VLAIO (SBO project CO2PERATE) and the Special Research Fund (BOF) of Ghent University. Funding of the iBOF project C3 (BOF20/IBF/010) is also gratefully acknowledged. K. V. H., M. B. and C. S. J. C. thank the Research Foundation – Flanders (FWO) for funding. The FWO is also gratefully acknowledged for PhD fellowships to B. P. M (1SB5321N) and N. V. T (11I6921N). Umicore AG and Johnson Matthey are thankfully acknowledged for generous gifts of materials.

PY - 2022/3/31

Y1 - 2022/3/31

N2 - A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed. The mechanism of this reaction is also elucidated $\textit{via}$ experimental and computational investigations. This straightforward protocol is then used for the synthesis of novel Pt(II)-NHC complexes and its utility is further explored to access key Pt(0)-NHC precatalysts.

AB - A sustainable and facile weak-base synthetic route to platinum N-heterocyclic carbene (NHC) complexes is disclosed. The mechanism of this reaction is also elucidated $\textit{via}$ experimental and computational investigations. This straightforward protocol is then used for the synthesis of novel Pt(II)-NHC complexes and its utility is further explored to access key Pt(0)-NHC precatalysts.

UR - http://hdl.handle.net/10754/676116

UR - http://xlink.rsc.org/?DOI=D2DT00504B

U2 - 10.1039/d2dt00504b

DO - 10.1039/d2dt00504b

M3 - Article

C2 - 35357386

SN - 1477-9226

JO - Dalton transactions (Cambridge, England : 2003)

JF - Dalton transactions (Cambridge, England : 2003)

ER -

A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope.

Abstract

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CCDC 2143388: Experimental Crystal Structure Determination : (1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]-imidazol-2-ylidene)-dichloro-(pyridine)-platinum(ii) dichloromethane solvate

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A green route to platinum N-heterocyclic carbene complexes: mechanism and expanded scope.

Abstract

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CCDC 2143388: Experimental Crystal Structure Determination : (1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]-imidazol-2-ylidene)-dichloro-(pyridine)-platinum(ii) dichloromethane solvate

Cite this