A lignin-based membrane fabricated with a deep eutectic solvent

Abaynesh Yihdego Gebreyohannes, Sandra L. Aristizábal, Liliana Silva, Eyad A. Qasem, Stefan Chisca, Lakshmeesha Upadhyaya, Daniyah Althobaiti, João A.P. Coutinho, Suzana P. Nunes*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Membrane technology is a sustainable process of molecular separation and purification in the chemical and pharmaceutical industries, with lower energy consumption than traditional thermal methods. For sustainability reasons, the membrane fabrication itself needs to align with the 12 principles of green chemistry with low environmental impact, preferentially using natural polymers and green solvents. Membranes are currently mostly produced from petroleum-based polymers and organic solvents like dimethylformamide, which are not expected to be used in large amounts anymore. Lignin is a natural green polymer option, however its low solubility in mild solvents has limited its processability into membranes. We propose a sustainable membrane fabrication method using lignin fully dissolved in a green deep eutectic solvent (DES). The crosslinking with 5% epoxide in the aqueous medium enhanced the membrane stability, enabling its application in an aqueous and organic solvent medium. The resulting membrane had a molecular weight cut-off of 1.3 kg mol−1, a range relevant to molecular separation in the pharmaceutical and chemical industries.

Original languageEnglish (US)
Pages (from-to)4769-4780
Number of pages12
JournalGreen Chemistry
Volume25
Issue number12
DOIs
StatePublished - May 9 2023

ASJC Scopus subject areas

  • Environmental Chemistry
  • Pollution

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