Abstract
C5Me4HPMe2 reacts with 1-adamantyl azide to form the first example of a new family of cyclopentadienylideneaminophosphorane ligands (1). Metallation of 1 with Lu(CH2SiMe3)3-(THF)2 leads to the first cyclopentadienyl-phosphazene CGC 2, isolobal to known group 4 cyclopentadienyl-silylamido CGC systems.
Original language | English (US) |
---|---|
Pages (from-to) | 3805-3807 |
Number of pages | 3 |
Journal | European Journal of Inorganic Chemistry |
Issue number | 19 |
DOIs | |
State | Published - Oct 7 2005 |
Externally published | Yes |
Keywords
- Bridging ligands
- Constrained geometry complexes
- Isolobal relationship
- Lutetium
- Phosphazenes
ASJC Scopus subject areas
- Inorganic Chemistry