A microporous lanthanide-organic framework

Theresa M. Reineke; Mohamed Eddaoudi; M. O'Keeffe; Omar M. Yaghi

doi:10.1002/(SICI)1521-3773(19990903)38:17<2590::AID-ANIE2590>3.0.CO;2-H

A microporous lanthanide-organic framework

Theresa M. Reineke, Mohamed Eddaoudi, M. O'Keeffe, Omar M. Yaghi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

503 Scopus citations

Abstract

Stable zeolite-like microporosity, even in the absence of guest molecules, is exhibited by a lanthanide-benzenedicarboxylate (BDC) framework, which was synthesized by the copolymerization of Tb(III) and 1,4- benzenedicarboxylic acid. The open Tb-BDC framework adopts an expanded PtS network structure (see diagram; Tb: open circles; C: full circles; lines connecting Tb to C represent O atoms, and those connecting C atoms are benzene rings) and is capable of reversible gas and liquid sorption.

Original language	English (US)
Pages (from-to)	2590-2594
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	17
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990903)38:17<2590::AID-ANIE2590>3.0.CO;2-H
State	Published - Sep 3 1999
Externally published	Yes

Keywords

Host-guest chemistry
Lanthanides
Microporosity
Zeolite anlogues

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/(SICI)1521-3773(19990903)38:17<2590::AID-ANIE2590>3.0.CO;2-H

Cite this

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title = "A microporous lanthanide-organic framework",

abstract = "Stable zeolite-like microporosity, even in the absence of guest molecules, is exhibited by a lanthanide-benzenedicarboxylate (BDC) framework, which was synthesized by the copolymerization of Tb(III) and 1,4- benzenedicarboxylic acid. The open Tb-BDC framework adopts an expanded PtS network structure (see diagram; Tb: open circles; C: full circles; lines connecting Tb to C represent O atoms, and those connecting C atoms are benzene rings) and is capable of reversible gas and liquid sorption.",

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AU - Eddaoudi, Mohamed

AU - O'Keeffe, M.

AU - Yaghi, Omar M.

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Y1 - 1999/9/3

N2 - Stable zeolite-like microporosity, even in the absence of guest molecules, is exhibited by a lanthanide-benzenedicarboxylate (BDC) framework, which was synthesized by the copolymerization of Tb(III) and 1,4- benzenedicarboxylic acid. The open Tb-BDC framework adopts an expanded PtS network structure (see diagram; Tb: open circles; C: full circles; lines connecting Tb to C represent O atoms, and those connecting C atoms are benzene rings) and is capable of reversible gas and liquid sorption.

AB - Stable zeolite-like microporosity, even in the absence of guest molecules, is exhibited by a lanthanide-benzenedicarboxylate (BDC) framework, which was synthesized by the copolymerization of Tb(III) and 1,4- benzenedicarboxylic acid. The open Tb-BDC framework adopts an expanded PtS network structure (see diagram; Tb: open circles; C: full circles; lines connecting Tb to C represent O atoms, and those connecting C atoms are benzene rings) and is capable of reversible gas and liquid sorption.

KW - Host-guest chemistry

KW - Lanthanides

KW - Microporosity

KW - Zeolite anlogues

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A microporous lanthanide-organic framework

Abstract

Keywords

ASJC Scopus subject areas

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