A new 2D honeycomb-like cluster polymer built by a {Mn6Na 3} cluster: Synthesis and magnetic property

Yun En Xie; Chong Bing Tian; Hua Bin Zhang; Yan Peng; Xian Qiang Li; Zhi Hua Li; Ping Lin; Shao Wu Du

doi:10.1016/j.inoche.2011.10.023

A new 2D honeycomb-like cluster polymer built by a {Mn6Na 3} cluster: Synthesis and magnetic property

Yun En Xie, Chong Bing Tian, Hua Bin Zhang, Yan Peng, Xian Qiang Li, Zhi Hua Li, Ping Lin, Shao Wu Du

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A new 2D polymer, {[Mn6Na3(μ6-O)(thme) 4(PhCO2)6(μ-H2O) 3][OH]}n (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the {Mn 6Na3} clusters. © 2011 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	198-201
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	15
DOIs	https://doi.org/10.1016/j.inoche.2011.10.023
State	Published - Jan 1 2012
Externally published	Yes

ASJC Scopus subject areas

Materials Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1016/j.inoche.2011.10.023

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abstract = "A new 2D polymer, {[Mn6Na3(μ6-O)(thme) 4(PhCO2)6(μ-H2O) 3][OH]}n (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the {Mn 6Na3} clusters. {\textcopyright} 2011 Elsevier B.V. All rights reserved.",

author = "Xie, {Yun En} and Tian, {Chong Bing} and Zhang, {Hua Bin} and Yan Peng and Li, {Xian Qiang} and Li, {Zhi Hua} and Ping Lin and Du, {Shao Wu}",

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AU - Xie, Yun En

AU - Tian, Chong Bing

AU - Zhang, Hua Bin

AU - Peng, Yan

AU - Li, Xian Qiang

AU - Li, Zhi Hua

AU - Lin, Ping

AU - Du, Shao Wu

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PY - 2012/1/1

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N2 - A new 2D polymer, {[Mn6Na3(μ6-O)(thme) 4(PhCO2)6(μ-H2O) 3][OH]}n (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the {Mn 6Na3} clusters. © 2011 Elsevier B.V. All rights reserved.

AB - A new 2D polymer, {[Mn6Na3(μ6-O)(thme) 4(PhCO2)6(μ-H2O) 3][OH]}n (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the {Mn 6Na3} clusters. © 2011 Elsevier B.V. All rights reserved.

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JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A new 2D honeycomb-like cluster polymer built by a {Mn6Na 3} cluster: Synthesis and magnetic property

Abstract

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