Abstract
A new 2D polymer, {[Mn6Na3(μ6-O)(thme) 4(PhCO2)6(μ-H2O) 3][OH]}n (1), has been synthesized and characterized by single crystal X-ray diffraction, XRD, IR spectroscopy, thermogravimetric analysis (TGA) and magnetic measurements. Compound 1 has a 2D honeycomb-like structure constructed by heterometallic {Mn6Na3} clusters, which are linked by water molecules cross-bridged between the Na (I) ions of the adjacent clusters. Magnetic property study reveals the existence of antiferromagnetic couplings between Mn (III) ions within the {Mn 6Na3} clusters. © 2011 Elsevier B.V. All rights reserved.
Original language | English (US) |
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Pages (from-to) | 198-201 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 15 |
DOIs | |
State | Published - Jan 1 2012 |
Externally published | Yes |
ASJC Scopus subject areas
- Materials Chemistry
- Physical and Theoretical Chemistry
- Inorganic Chemistry