A rapid, orthogonal synthesis of poly(benzyl ester) dendrimers via an "activated" monomer approach

Adam W. Freeman; Jean M.J. Fréchet

doi:10.1021/ol9907724

A rapid, orthogonal synthesis of poly(benzyl ester) dendrimers via an "activated" monomer approach

Adam W. Freeman, Jean M.J. Fréchet^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

(Matrix presented) Herein we introduce the concept of an "activated" monomer approach to the synthesis of convergent dendrimers. In this method a set of chemically orthogonal monomers, one of which is an "activated" analogue of the other, is used to rapidly synthesize large, perfect dendrimers with one additional generation being added in each reaction. This method is exemplified by the efficient preparation of a new family of poly(benzyl ester) dendrimers described below.

Original language	English (US)
Pages (from-to)	685-687
Number of pages	3
Journal	Organic Letters
Volume	1
Issue number	4
DOIs	https://doi.org/10.1021/ol9907724
State	Published - Aug 26 1999
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol9907724

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AU - Fréchet, Jean M.J.

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N2 - (Matrix presented) Herein we introduce the concept of an "activated" monomer approach to the synthesis of convergent dendrimers. In this method a set of chemically orthogonal monomers, one of which is an "activated" analogue of the other, is used to rapidly synthesize large, perfect dendrimers with one additional generation being added in each reaction. This method is exemplified by the efficient preparation of a new family of poly(benzyl ester) dendrimers described below.

AB - (Matrix presented) Herein we introduce the concept of an "activated" monomer approach to the synthesis of convergent dendrimers. In this method a set of chemically orthogonal monomers, one of which is an "activated" analogue of the other, is used to rapidly synthesize large, perfect dendrimers with one additional generation being added in each reaction. This method is exemplified by the efficient preparation of a new family of poly(benzyl ester) dendrimers described below.

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U2 - 10.1021/ol9907724

DO - 10.1021/ol9907724

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A rapid, orthogonal synthesis of poly(benzyl ester) dendrimers via an "activated" monomer approach

Abstract

ASJC Scopus subject areas

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