A simple route to multifunctional phosphide and amide donor sets; Syntheses and structures of [{Bu(t)PAs(NMe2)2}K·pmdeta]2 and [{CyNAs(NMe2)2K}2](∞)

Michael A. Beswick*, Alan Bashall, Alexander D. Hopkins, Sara J. Kidd, Yvonne G. Lawson, Mary McPartlin, Paul R. Raithby, Alexander Rothenberger, Dietmar Stalke, Dominic S. Wright

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The syntheses of [Bu(t)PAs(NMe2)2K·pmedta]2 1 and [{CyNAs(NMe2)2K}2](∞) 2 from the reactions of [As(NMe2)3] with Bu(t)PH2 and CyNH2, respectively, in the presence of potassiated bases exemplify a general approach to multifunctional secondary phosphide and amide anions containing variable sets of group 15 donor centres.

Original languageEnglish (US)
Pages (from-to)739-740
Number of pages2
JournalCHEMICAL COMMUNICATIONS
Issue number8
DOIs
StatePublished - Apr 21 1999
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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