TY - JOUR
T1 - A zeolite-like Metal-Organic Framework Based Membrane for Reverse Selective Hydrogen Separation and Butane Isomers Sieving
AU - Chernikova, Valeriya
AU - Shekhah, Osama
AU - Belmabkhout, Youssef
AU - Karunakaran, Madhavan
AU - Eddaoudi, Mohamed
N1 - KAUST Repository Item: Exported on 2023-02-13
Acknowledgements: This work was financially supported by King Abdullah University of science and technology.
PY - 2023/2/10
Y1 - 2023/2/10
N2 - Here, the fabrication of a defect-free membrane that is based on a zeolite-like metal-organic framework (ZMOF) with the underlying ana topology is reported. The unique ana-ZMOF structure provides high degree of pore connectivity, which is reflected by the fast transport of gases. Prominently, it offers an optimum pore-aperture size, affording notable sieving selectivity for butane/isobutane, and optimal pore energetics for reverse CO2/H2 separation. This emphasize the potential for the application of pure MOF membranes, paving the way to more sustainability of energy resources.
AB - Here, the fabrication of a defect-free membrane that is based on a zeolite-like metal-organic framework (ZMOF) with the underlying ana topology is reported. The unique ana-ZMOF structure provides high degree of pore connectivity, which is reflected by the fast transport of gases. Prominently, it offers an optimum pore-aperture size, affording notable sieving selectivity for butane/isobutane, and optimal pore energetics for reverse CO2/H2 separation. This emphasize the potential for the application of pure MOF membranes, paving the way to more sustainability of energy resources.
UR - http://hdl.handle.net/10754/687683
UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.202218842
U2 - 10.1002/anie.202218842
DO - 10.1002/anie.202218842
M3 - Article
C2 - 36762967
SN - 1433-7851
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
ER -