Abstract
Pseudo-achiral metal-centre driven spontaneous resolution occurred simultaneously in the formation of two Δ- and Λ-isomers of [CdBa(OBA)2(DMF)(CH3OH)(H2O)]·H 2O (H2OBA = 4,4′-oxybis(benzoic acid)), which illustrated a clear relationship between chirality and helicity: the absolute sense of a double-helix made of achiral components is induced by metal centres in the two enantiomeric forms. © 2014 The Royal Society of Chemistry.
Original language | English (US) |
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Pages (from-to) | 1245-1248 |
Number of pages | 4 |
Journal | CrystEngComm |
Volume | 16 |
Issue number | 7 |
DOIs | |
State | Published - Feb 21 2014 |
Externally published | Yes |
ASJC Scopus subject areas
- General Materials Science
- General Chemistry
- Condensed Matter Physics