Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation

Charbel Roukoss; Steven Fiddy; Aimery De Mallmann; Nuria Rendón; Jean Marie Basset; Emile Kuntz; Christophe Copéret

doi:10.1039/b711015d

Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation

Charbel Roukoss, Steven Fiddy, Aimery De Mallmann, Nuria Rendón, Jean Marie Basset, Emile Kuntz, Christophe Copéret^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Well-defined Fe^II isolated sites are obtained by reaction of diaryl-N,N′-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO_2-(700). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H₂O₂.

Original language	English (US)
Pages (from-to)	5546-5548
Number of pages	3
Journal	Dalton transactions
Issue number	47
DOIs	https://doi.org/10.1039/b711015d
State	Published - 2007
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/b711015d

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title = "Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation",

abstract = "Well-defined FeII isolated sites are obtained by reaction of diaryl-N,N′-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO2-(700). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H2O2.",

author = "Charbel Roukoss and Steven Fiddy and {De Mallmann}, Aimery and Nuria Rend{\'o}n and Basset, {Jean Marie} and Emile Kuntz and Christophe Cop{\'e}ret",

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pages = "5546--5548",

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T1 - Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation

AU - Roukoss, Charbel

AU - Fiddy, Steven

AU - De Mallmann, Aimery

AU - Rendón, Nuria

AU - Basset, Jean Marie

AU - Kuntz, Emile

AU - Copéret, Christophe

PY - 2007

Y1 - 2007

N2 - Well-defined FeII isolated sites are obtained by reaction of diaryl-N,N′-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO2-(700). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H2O2.

AB - Well-defined FeII isolated sites are obtained by reaction of diaryl-N,N′-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO2-(700). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H2O2.

UR - http://www.scopus.com/inward/record.url?scp=36448936421&partnerID=8YFLogxK

U2 - 10.1039/b711015d

DO - 10.1039/b711015d

M3 - Article

C2 - 18043815

AN - SCOPUS:36448936421

SN - 1477-9226

SP - 5546

EP - 5548

JO - Dalton transactions

JF - Dalton transactions

IS - 47

ER -

Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation

Abstract

ASJC Scopus subject areas

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