Acrylamide-based amphiphilic block copolymers via nitroxide-mediated radical polymerization

K. Schierholz; M. Givehchi; P. Fabre; F. Nallet; E. Papon; O. Guerret; Y. Gnanou

doi:10.1021/ma0300387

Acrylamide-based amphiphilic block copolymers via nitroxide-mediated radical polymerization

K. Schierholz, M. Givehchi, P. Fabre, F. Nallet, E. Papon, O. Guerret, Y. Gnanou^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

84 Scopus citations

Abstract

Nitroxide-mediated polymerization is shown to produce well-defined poly(N,N-dimethylacrylamide) samples. In the presence of SG1, a β-phosphonylated nitroxide, the free radical polymerization of N,N-dimethylacrylamide indeed exhibits a "living"/controlled character, provided the nitroxide is used in excess and its concentration finely tuned as compared to that the free radical initiator (AIBN). Poly(N,N-dimethylacrylamide-b-butyl acrylate) diblocks copolymers were subsequently derived by sequential polymerization of the two corresponding monomers.

Original language	English (US)
Pages (from-to)	5995-5999
Number of pages	5
Journal	Macromolecules
Volume	36
Issue number	16
DOIs	https://doi.org/10.1021/ma0300387
State	Published - Aug 12 2003
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1021/ma0300387

Cite this

@article{7d70a26b673d4635805d547556a23acc,

title = "Acrylamide-based amphiphilic block copolymers via nitroxide-mediated radical polymerization",

abstract = "Nitroxide-mediated polymerization is shown to produce well-defined poly(N,N-dimethylacrylamide) samples. In the presence of SG1, a β-phosphonylated nitroxide, the free radical polymerization of N,N-dimethylacrylamide indeed exhibits a {"}living{"}/controlled character, provided the nitroxide is used in excess and its concentration finely tuned as compared to that the free radical initiator (AIBN). Poly(N,N-dimethylacrylamide-b-butyl acrylate) diblocks copolymers were subsequently derived by sequential polymerization of the two corresponding monomers.",

author = "K. Schierholz and M. Givehchi and P. Fabre and F. Nallet and E. Papon and O. Guerret and Y. Gnanou",

year = "2003",

month = aug,

day = "12",

doi = "10.1021/ma0300387",

language = "English (US)",

volume = "36",

pages = "5995--5999",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "16",

}

TY - JOUR

T1 - Acrylamide-based amphiphilic block copolymers via nitroxide-mediated radical polymerization

AU - Schierholz, K.

AU - Givehchi, M.

AU - Fabre, P.

AU - Nallet, F.

AU - Papon, E.

AU - Guerret, O.

AU - Gnanou, Y.

PY - 2003/8/12

Y1 - 2003/8/12

N2 - Nitroxide-mediated polymerization is shown to produce well-defined poly(N,N-dimethylacrylamide) samples. In the presence of SG1, a β-phosphonylated nitroxide, the free radical polymerization of N,N-dimethylacrylamide indeed exhibits a "living"/controlled character, provided the nitroxide is used in excess and its concentration finely tuned as compared to that the free radical initiator (AIBN). Poly(N,N-dimethylacrylamide-b-butyl acrylate) diblocks copolymers were subsequently derived by sequential polymerization of the two corresponding monomers.

AB - Nitroxide-mediated polymerization is shown to produce well-defined poly(N,N-dimethylacrylamide) samples. In the presence of SG1, a β-phosphonylated nitroxide, the free radical polymerization of N,N-dimethylacrylamide indeed exhibits a "living"/controlled character, provided the nitroxide is used in excess and its concentration finely tuned as compared to that the free radical initiator (AIBN). Poly(N,N-dimethylacrylamide-b-butyl acrylate) diblocks copolymers were subsequently derived by sequential polymerization of the two corresponding monomers.

UR - http://www.scopus.com/inward/record.url?scp=0041473866&partnerID=8YFLogxK

U2 - 10.1021/ma0300387

DO - 10.1021/ma0300387

M3 - Article

AN - SCOPUS:0041473866

SN - 0024-9297

VL - 36

SP - 5995

EP - 5999

JO - Macromolecules

JF - Macromolecules

IS - 16

ER -

Acrylamide-based amphiphilic block copolymers via nitroxide-mediated radical polymerization

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this