Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species

M. Mihaylov; K. Chakarova; S. Andonova; N. Drenchev; E. Ivanova; E. A. Pidko; A. Sabetghadam; B. Seoane; J. Gascon; F. Kapteijn; K. Hadjiivanov

doi:10.1039/c5cc08677a

Adsorption of CO₂ on MIL-53(Al): FTIR evidence of the formation of dimeric CO₂ species

M. Mihaylov, K. Chakarova, S. Andonova, N. Drenchev, E. Ivanova, E. A. Pidko, A. Sabetghadam, B. Seoane, J. Gascon, F. Kapteijn, K. Hadjiivanov^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

FTIR spectra of ¹²CO₂ and ¹²CO₂ + ¹³CO₂ mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO₂)₂ species connected to two structural OH groups.

Original language	English (US)
Pages (from-to)	1494-1497
Number of pages	4
Journal	CHEMICAL COMMUNICATIONS
Volume	52
Issue number	7
DOIs	https://doi.org/10.1039/c5cc08677a
State	Published - Jan 25 2016
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species",

abstract = "FTIR spectra of 12CO2 and 12CO2 + 13CO2 mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO2)2 species connected to two structural OH groups.",

author = "M. Mihaylov and K. Chakarova and S. Andonova and N. Drenchev and E. Ivanova and Pidko, {E. A.} and A. Sabetghadam and B. Seoane and J. Gascon and F. Kapteijn and K. Hadjiivanov",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2016",

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doi = "10.1039/c5cc08677a",

language = "English (US)",

volume = "52",

pages = "1494--1497",

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T1 - Adsorption of CO2 on MIL-53(Al)

T2 - FTIR evidence of the formation of dimeric CO2 species

AU - Mihaylov, M.

AU - Chakarova, K.

AU - Andonova, S.

AU - Drenchev, N.

AU - Ivanova, E.

AU - Pidko, E. A.

AU - Sabetghadam, A.

AU - Seoane, B.

AU - Gascon, J.

AU - Kapteijn, F.

AU - Hadjiivanov, K.

PY - 2016/1/25

Y1 - 2016/1/25

N2 - FTIR spectra of 12CO2 and 12CO2 + 13CO2 mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO2)2 species connected to two structural OH groups.

AB - FTIR spectra of 12CO2 and 12CO2 + 13CO2 mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO2)2 species connected to two structural OH groups.

UR - http://www.scopus.com/inward/record.url?scp=84954446515&partnerID=8YFLogxK

U2 - 10.1039/c5cc08677a

DO - 10.1039/c5cc08677a

M3 - Article

C2 - 26659642

AN - SCOPUS:84954446515

SN - 1359-7345

VL - 52

SP - 1494

EP - 1497

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 7

ER -

Adsorption of CO₂ on MIL-53(Al): FTIR evidence of the formation of dimeric CO₂ species

Abstract

ASJC Scopus subject areas

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