Aggregation and surface morphology of a poly(ethylene oxide)-block-polystyrene three-arm star polymer at the air/water interface studied by AFM

Raju Francis; Andrew M. Skolnik; Stephen R. Carino; Jennifer L. Logan; Royale S. Underhill; Stéphanie Angot; Daniel Taton; Yves Gnanou; Randolph S. Duran

doi:10.1021/ma020290z

Aggregation and surface morphology of a poly(ethylene oxide)-block-polystyrene three-arm star polymer at the air/water interface studied by AFM

Raju Francis, Andrew M. Skolnik, Stephen R. Carino, Jennifer L. Logan, Royale S. Underhill, Stéphanie Angot, Daniel Taton, Yves Gnanou, Randolph S. Duran^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

45 Scopus citations

Abstract

The behavior of a three-arm star amphiphilic copolymer, PEO₃-b-PSD₃ were investigated at the air/water interface through atomic force microscopy (AFM) images of the monolayer on mica. The Langmuir-Blodgett (LB) films were prepared on the KSV 5000 system with a platinum Wilhelmy plate. The PEO₃-b-PS₃ three arm star used were prepared by the anionic polymerization of ethylene oxide followed by the ATRP synthesis of styrene. It was assumed that the characteristics of the monolayer at the air/water interface remained unchanged upon transfer to the mica surface.

Original language	English (US)
Pages (from-to)	6483-6485
Number of pages	3
Journal	Macromolecules
Volume	35
Issue number	17
DOIs	https://doi.org/10.1021/ma020290z
State	Published - Aug 13 2002
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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@article{368eeb86efcf48268e19ba909352b74b,

title = "Aggregation and surface morphology of a poly(ethylene oxide)-block-polystyrene three-arm star polymer at the air/water interface studied by AFM",

abstract = "The behavior of a three-arm star amphiphilic copolymer, PEO3-b-PSD3 were investigated at the air/water interface through atomic force microscopy (AFM) images of the monolayer on mica. The Langmuir-Blodgett (LB) films were prepared on the KSV 5000 system with a platinum Wilhelmy plate. The PEO3-b-PS3 three arm star used were prepared by the anionic polymerization of ethylene oxide followed by the ATRP synthesis of styrene. It was assumed that the characteristics of the monolayer at the air/water interface remained unchanged upon transfer to the mica surface.",

author = "Raju Francis and Skolnik, {Andrew M.} and Carino, {Stephen R.} and Logan, {Jennifer L.} and Underhill, {Royale S.} and St{\'e}phanie Angot and Daniel Taton and Yves Gnanou and Duran, {Randolph S.}",

year = "2002",

month = aug,

day = "13",

doi = "10.1021/ma020290z",

language = "English (US)",

volume = "35",

pages = "6483--6485",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Aggregation and surface morphology of a poly(ethylene oxide)-block-polystyrene three-arm star polymer at the air/water interface studied by AFM

AU - Francis, Raju

AU - Skolnik, Andrew M.

AU - Carino, Stephen R.

AU - Logan, Jennifer L.

AU - Underhill, Royale S.

AU - Angot, Stéphanie

AU - Taton, Daniel

AU - Gnanou, Yves

AU - Duran, Randolph S.

PY - 2002/8/13

Y1 - 2002/8/13

N2 - The behavior of a three-arm star amphiphilic copolymer, PEO3-b-PSD3 were investigated at the air/water interface through atomic force microscopy (AFM) images of the monolayer on mica. The Langmuir-Blodgett (LB) films were prepared on the KSV 5000 system with a platinum Wilhelmy plate. The PEO3-b-PS3 three arm star used were prepared by the anionic polymerization of ethylene oxide followed by the ATRP synthesis of styrene. It was assumed that the characteristics of the monolayer at the air/water interface remained unchanged upon transfer to the mica surface.

AB - The behavior of a three-arm star amphiphilic copolymer, PEO3-b-PSD3 were investigated at the air/water interface through atomic force microscopy (AFM) images of the monolayer on mica. The Langmuir-Blodgett (LB) films were prepared on the KSV 5000 system with a platinum Wilhelmy plate. The PEO3-b-PS3 three arm star used were prepared by the anionic polymerization of ethylene oxide followed by the ATRP synthesis of styrene. It was assumed that the characteristics of the monolayer at the air/water interface remained unchanged upon transfer to the mica surface.

UR - http://www.scopus.com/inward/record.url?scp=0037072337&partnerID=8YFLogxK

U2 - 10.1021/ma020290z

DO - 10.1021/ma020290z

M3 - Review article

AN - SCOPUS:0037072337

SN - 0024-9297

VL - 35

SP - 6483

EP - 6485

JO - Macromolecules

JF - Macromolecules

IS - 17

ER -

Aggregation and surface morphology of a poly(ethylene oxide)-block-polystyrene three-arm star polymer at the air/water interface studied by AFM

Abstract

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