Allyl borates: a novel class of polyhomologation initiators

De Wang; Nikos Hadjichristidis

doi:10.1039/c6cc09047h

Allyl borates: a novel class of polyhomologation initiators

De Wang, Nikos Hadjichristidis

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Allyl borates, a new class of monofunctional polyhomologation initiators, are reported. These monofunctional initiators are less sensitive and more effective towards polymethylene-based architectures. As an example, the synthesis of α-vinyl-ω-hydroxypolymethylenes is given. By designing/synthesizing different allylic borate initiators, and using 1H and 11B NMR spectroscopy, the initiation mechanism was elucidated.

Original language	English (US)
Pages (from-to)	1196-1199
Number of pages	4
Journal	Chem. Commun.
Volume	53
Issue number	6
DOIs	https://doi.org/10.1039/c6cc09047h
State	Published - 2017

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title = "Allyl borates: a novel class of polyhomologation initiators",

abstract = "Allyl borates, a new class of monofunctional polyhomologation initiators, are reported. These monofunctional initiators are less sensitive and more effective towards polymethylene-based architectures. As an example, the synthesis of α-vinyl-ω-hydroxypolymethylenes is given. By designing/synthesizing different allylic borate initiators, and using 1H and 11B NMR spectroscopy, the initiation mechanism was elucidated.",

author = "De Wang and Nikos Hadjichristidis",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).",

year = "2017",

doi = "10.1039/c6cc09047h",

language = "English (US)",

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pages = "1196--1199",

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AU - Wang, De

AU - Hadjichristidis, Nikos

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).

PY - 2017

Y1 - 2017

N2 - Allyl borates, a new class of monofunctional polyhomologation initiators, are reported. These monofunctional initiators are less sensitive and more effective towards polymethylene-based architectures. As an example, the synthesis of α-vinyl-ω-hydroxypolymethylenes is given. By designing/synthesizing different allylic borate initiators, and using 1H and 11B NMR spectroscopy, the initiation mechanism was elucidated.

AB - Allyl borates, a new class of monofunctional polyhomologation initiators, are reported. These monofunctional initiators are less sensitive and more effective towards polymethylene-based architectures. As an example, the synthesis of α-vinyl-ω-hydroxypolymethylenes is given. By designing/synthesizing different allylic borate initiators, and using 1H and 11B NMR spectroscopy, the initiation mechanism was elucidated.

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JO - Chem. Commun.

JF - Chem. Commun.

IS - 6

ER -

Allyl borates: a novel class of polyhomologation initiators

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