Abstract
We study asymmetric block copolymers with the simple diblock AB architecture, in the case where the longer block A is both hydrophobic and "soft", whereas the shorter block B is hydrophilic and "hard". Materials with such a particular combination of physico-chemical and mechanical properties have distinctive advantages, in particular for designing water-compatible adhesive materials. The phase diagram is established, combining NMR and SAXS characterisations of the materials. The swelling with water is monitored through gravimetry and "time- resolved" SAXS. Indications of maintained adhesive properties in a wet environment are given.
Original language | English (US) |
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Pages (from-to) | 273-287 |
Number of pages | 15 |
Journal | European Physical Journal E |
Volume | 20 |
Issue number | 3 |
DOIs | |
State | Published - Jul 2006 |
Externally published | Yes |
ASJC Scopus subject areas
- Biotechnology
- Biophysics
- General Chemistry
- General Materials Science
- Surfaces and Interfaces