An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band

Chad Risko; Stephen Barlow; Veaceslav Coropceanu; Marcus Halik; Jean Luc Brédas; Seth R. Marder

doi:10.1039/b210429f

An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band

Chad Risko, Stephen Barlow^*, Veaceslav Coropceanu, Marcus Halik, Jean Luc Brédas, Seth R. Marder

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The reduction of a phenylene-bridged bis(dioxaborine) affords a strongly delocalised organic mixed-valence system; for the first time details of the vibrations coupled to the electron transfer have been extracted from the intervalence band.

Original language	English (US)
Pages (from-to)	194-195
Number of pages	2
Journal	CHEMICAL COMMUNICATIONS
Issue number	2
DOIs	https://doi.org/10.1039/b210429f
State	Published - 2003
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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title = "An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band",

abstract = "The reduction of a phenylene-bridged bis(dioxaborine) affords a strongly delocalised organic mixed-valence system; for the first time details of the vibrations coupled to the electron transfer have been extracted from the intervalence band.",

author = "Chad Risko and Stephen Barlow and Veaceslav Coropceanu and Marcus Halik and Br{\'e}das, {Jean Luc} and Marder, {Seth R.}",

year = "2003",

doi = "10.1039/b210429f",

language = "English (US)",

pages = "194--195",

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T1 - An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band

AU - Risko, Chad

AU - Barlow, Stephen

AU - Coropceanu, Veaceslav

AU - Halik, Marcus

AU - Brédas, Jean Luc

AU - Marder, Seth R.

PY - 2003

Y1 - 2003

N2 - The reduction of a phenylene-bridged bis(dioxaborine) affords a strongly delocalised organic mixed-valence system; for the first time details of the vibrations coupled to the electron transfer have been extracted from the intervalence band.

AB - The reduction of a phenylene-bridged bis(dioxaborine) affords a strongly delocalised organic mixed-valence system; for the first time details of the vibrations coupled to the electron transfer have been extracted from the intervalence band.

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U2 - 10.1039/b210429f

DO - 10.1039/b210429f

M3 - Article

C2 - 12585387

AN - SCOPUS:0037242057

SN - 1359-7345

SP - 194

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JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 2

ER -

An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band

Abstract

ASJC Scopus subject areas

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