Abstract
An anodic alumina supported Ni-Pt bimetallic plate-type catalyst was prepared by a two-step impregnation method. The trace amount 0.08 wt% of Pt doping efficiently suppressed the nickel particle sintering and improved the nickel oxides reducibility. The prepared Ni-Pt catalyst showed excellent performance during steam reforming of methane, kerosene and ethanol under both 3000 h stationary and 500-time daily start-up and shut-down operation modes. Self-activation ability of this catalyst was evidenced, which was considered to be resulted from the hydrogen spillover effect over Ni-Pt alloy. In addition, an integrated combustion-reforming reactor was proposed in this study. However, the sintering of the alumina support is still a critical issue for the industrialization of Ni-Pt catalyst. Copyright © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
Original language | English (US) |
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Pages (from-to) | 7291-7305 |
Number of pages | 15 |
Journal | International Journal of Hydrogen Energy |
Volume | 39 |
Issue number | 14 |
DOIs | |
State | Published - May 2014 |
ASJC Scopus subject areas
- Energy Engineering and Power Technology
- Condensed Matter Physics
- Fuel Technology
- Renewable Energy, Sustainability and the Environment