An effective approach for constructing acentric heterometallic-organic framework with catalytic activity

Yan Fei Chen; Yun Cui Ma; Hua Bin Zhang; Shu Mei Chen

doi:10.1016/j.inoche.2014.01.021

An effective approach for constructing acentric heterometallic-organic framework with catalytic activity

Yan Fei Chen, Yun Cui Ma, Hua Bin Zhang, Shu Mei Chen

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A new acentric heterometallic-organic framework, [CdMg (btec)(DMF)(H 2O)3] (1) (H4btec = 1,2,4,5-benzene tetracarboxylic acid), has been solvothermally synthesized. It features a 4-connected net with typical pts topology. To the best of our knowledge, compound 1 is the first example of Cd-Mg heterometallic organic framework based on the H4btec ligand. Compound 1 has potential unsaturated metal sites after the removal of coordination water molecules, so it shows good catalytic activity on the diethylzinc addition to benzaldehyde. The photoluminescent property of 1 is also investigated. © 2014 Elsevier B.V.

Original language	English (US)
Pages (from-to)	27-30
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	43
DOIs	https://doi.org/10.1016/j.inoche.2014.01.021
State	Published - May 1 2014
Externally published	Yes

ASJC Scopus subject areas

Materials Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1016/j.inoche.2014.01.021

Cite this

@article{b3f8a4a3eb984cffbcaf9c1d523151df,

title = "An effective approach for constructing acentric heterometallic-organic framework with catalytic activity",

abstract = "A new acentric heterometallic-organic framework, [CdMg (btec)(DMF)(H 2O)3] (1) (H4btec = 1,2,4,5-benzene tetracarboxylic acid), has been solvothermally synthesized. It features a 4-connected net with typical pts topology. To the best of our knowledge, compound 1 is the first example of Cd-Mg heterometallic organic framework based on the H4btec ligand. Compound 1 has potential unsaturated metal sites after the removal of coordination water molecules, so it shows good catalytic activity on the diethylzinc addition to benzaldehyde. The photoluminescent property of 1 is also investigated. {\textcopyright} 2014 Elsevier B.V.",

author = "Chen, {Yan Fei} and Ma, {Yun Cui} and Zhang, {Hua Bin} and Chen, {Shu Mei}",

note = "Generated from Scopus record by KAUST IRTS on 2022-09-15",

year = "2014",

month = may,

day = "1",

doi = "10.1016/j.inoche.2014.01.021",

language = "English (US)",

volume = "43",

pages = "27--30",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - An effective approach for constructing acentric heterometallic-organic framework with catalytic activity

AU - Chen, Yan Fei

AU - Ma, Yun Cui

AU - Zhang, Hua Bin

AU - Chen, Shu Mei

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2014/5/1

Y1 - 2014/5/1

N2 - A new acentric heterometallic-organic framework, [CdMg (btec)(DMF)(H 2O)3] (1) (H4btec = 1,2,4,5-benzene tetracarboxylic acid), has been solvothermally synthesized. It features a 4-connected net with typical pts topology. To the best of our knowledge, compound 1 is the first example of Cd-Mg heterometallic organic framework based on the H4btec ligand. Compound 1 has potential unsaturated metal sites after the removal of coordination water molecules, so it shows good catalytic activity on the diethylzinc addition to benzaldehyde. The photoluminescent property of 1 is also investigated. © 2014 Elsevier B.V.

AB - A new acentric heterometallic-organic framework, [CdMg (btec)(DMF)(H 2O)3] (1) (H4btec = 1,2,4,5-benzene tetracarboxylic acid), has been solvothermally synthesized. It features a 4-connected net with typical pts topology. To the best of our knowledge, compound 1 is the first example of Cd-Mg heterometallic organic framework based on the H4btec ligand. Compound 1 has potential unsaturated metal sites after the removal of coordination water molecules, so it shows good catalytic activity on the diethylzinc addition to benzaldehyde. The photoluminescent property of 1 is also investigated. © 2014 Elsevier B.V.

UR - https://linkinghub.elsevier.com/retrieve/pii/S1387700314000318

UR - http://www.scopus.com/inward/record.url?scp=84894762863&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2014.01.021

DO - 10.1016/j.inoche.2014.01.021

M3 - Article

SN - 1387-7003

VL - 43

SP - 27

EP - 30

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

An effective approach for constructing acentric heterometallic-organic framework with catalytic activity

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this