Analysis of proton-conducting organic-inorganic hybrid materials based on sulphonated poly(ether ether ketone) and phosphotungstic acid via ASAXS and WAXS

Luis A.S.de A. Prado; Mariela L. Ponce; Günter Goerigk; Sérgio S. Funari; Vasyl M. Garamus; Regine Willumeit; Karl Schulte; Suzana P. Nunes

doi:10.1016/j.jnoncrysol.2008.09.036

Analysis of proton-conducting organic-inorganic hybrid materials based on sulphonated poly(ether ether ketone) and phosphotungstic acid via ASAXS and WAXS

Luis A.S.de A. Prado^*, Mariela L. Ponce, Günter Goerigk, Sérgio S. Funari, Vasyl M. Garamus, Regine Willumeit, Karl Schulte, Suzana P. Nunes

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

In the present paper the distribution of phosphotungstic acid (PTA, H₃PW₁₂O₄₀) dispersed in sulfonated poly(ether ether ketone), SPEEK, was investigated by Anomalous Small Angle X-ray scattering (ASAXS) and Wide-Angle X-Ray Scattering WAXS techniques. The hydrolysis and condensation of 3-aminopropyltrimethoxysilane or zirconium tetrapropylate in this polymeric matrix were used to produce poly(3-aminopropyl silsesquioxane) or ZrO₂, as nanofillers. Contrary to previous results reported for membranes containing phosphomolybdic acid, the PTA could be completely dissolved in the SPEEK matrix. The applicability of the Guinier approximation for the SPEEK/PTA membrane confirmed that the PTA was dispersed as isolated nanoparticles. The incorporation of poly(3-aminopropyl silsesquioxane) in the SPEEK/PTA system caused the agglomeration of the heteropolyacid as 30 nm large particles. The ZrO₂ had little effect on the distribution of PTA in the SPEEK matrix. On the other hand, no crystallization of the heteropolyacid was observed in the membranes.

Original language	English (US)
Pages (from-to)	6-11
Number of pages	6
Journal	Journal of Non-Crystalline Solids
Volume	355
Issue number	1
DOIs	https://doi.org/10.1016/j.jnoncrysol.2008.09.036
State	Published - Jan 1 2009
Externally published	Yes

Keywords

Diffraction and scattering measurements
Nanoparticles, colloids and quantum structures
Organic-inorganic hybrids
Polymers and organics
X-ray diffraction

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

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10.1016/j.jnoncrysol.2008.09.036

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Prado, L. A. S. D. A., Ponce, M. L., Goerigk, G., Funari, S. S., Garamus, V. M., Willumeit, R., Schulte, K., & Nunes, S. P. (2009). Analysis of proton-conducting organic-inorganic hybrid materials based on sulphonated poly(ether ether ketone) and phosphotungstic acid via ASAXS and WAXS. Journal of Non-Crystalline Solids, 355(1), 6-11. https://doi.org/10.1016/j.jnoncrysol.2008.09.036

@article{f8737b8e0a2e4c368e24ba59c0c2f215,

title = "Analysis of proton-conducting organic-inorganic hybrid materials based on sulphonated poly(ether ether ketone) and phosphotungstic acid via ASAXS and WAXS",

abstract = "In the present paper the distribution of phosphotungstic acid (PTA, H3PW12O40) dispersed in sulfonated poly(ether ether ketone), SPEEK, was investigated by Anomalous Small Angle X-ray scattering (ASAXS) and Wide-Angle X-Ray Scattering WAXS techniques. The hydrolysis and condensation of 3-aminopropyltrimethoxysilane or zirconium tetrapropylate in this polymeric matrix were used to produce poly(3-aminopropyl silsesquioxane) or ZrO2, as nanofillers. Contrary to previous results reported for membranes containing phosphomolybdic acid, the PTA could be completely dissolved in the SPEEK matrix. The applicability of the Guinier approximation for the SPEEK/PTA membrane confirmed that the PTA was dispersed as isolated nanoparticles. The incorporation of poly(3-aminopropyl silsesquioxane) in the SPEEK/PTA system caused the agglomeration of the heteropolyacid as 30 nm large particles. The ZrO2 had little effect on the distribution of PTA in the SPEEK matrix. On the other hand, no crystallization of the heteropolyacid was observed in the membranes.",

keywords = "Diffraction and scattering measurements, Nanoparticles, colloids and quantum structures, Organic-inorganic hybrids, Polymers and organics, X-ray diffraction",

author = "Prado, {Luis A.S.de A.} and Ponce, {Mariela L.} and G{\"u}nter Goerigk and Funari, {S{\'e}rgio S.} and Garamus, {Vasyl M.} and Regine Willumeit and Karl Schulte and Nunes, {Suzana P.}",

year = "2009",

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doi = "10.1016/j.jnoncrysol.2008.09.036",

language = "English (US)",

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Prado, LASDA, Ponce, ML, Goerigk, G, Funari, SS, Garamus, VM, Willumeit, R, Schulte, K & Nunes, SP 2009, 'Analysis of proton-conducting organic-inorganic hybrid materials based on sulphonated poly(ether ether ketone) and phosphotungstic acid via ASAXS and WAXS', Journal of Non-Crystalline Solids, vol. 355, no. 1, pp. 6-11. https://doi.org/10.1016/j.jnoncrysol.2008.09.036

TY - JOUR

T1 - Analysis of proton-conducting organic-inorganic hybrid materials based on sulphonated poly(ether ether ketone) and phosphotungstic acid via ASAXS and WAXS

AU - Prado, Luis A.S.de A.

AU - Ponce, Mariela L.

AU - Goerigk, Günter

AU - Funari, Sérgio S.

AU - Garamus, Vasyl M.

AU - Willumeit, Regine

AU - Schulte, Karl

AU - Nunes, Suzana P.

PY - 2009/1/1

Y1 - 2009/1/1

N2 - In the present paper the distribution of phosphotungstic acid (PTA, H3PW12O40) dispersed in sulfonated poly(ether ether ketone), SPEEK, was investigated by Anomalous Small Angle X-ray scattering (ASAXS) and Wide-Angle X-Ray Scattering WAXS techniques. The hydrolysis and condensation of 3-aminopropyltrimethoxysilane or zirconium tetrapropylate in this polymeric matrix were used to produce poly(3-aminopropyl silsesquioxane) or ZrO2, as nanofillers. Contrary to previous results reported for membranes containing phosphomolybdic acid, the PTA could be completely dissolved in the SPEEK matrix. The applicability of the Guinier approximation for the SPEEK/PTA membrane confirmed that the PTA was dispersed as isolated nanoparticles. The incorporation of poly(3-aminopropyl silsesquioxane) in the SPEEK/PTA system caused the agglomeration of the heteropolyacid as 30 nm large particles. The ZrO2 had little effect on the distribution of PTA in the SPEEK matrix. On the other hand, no crystallization of the heteropolyacid was observed in the membranes.

AB - In the present paper the distribution of phosphotungstic acid (PTA, H3PW12O40) dispersed in sulfonated poly(ether ether ketone), SPEEK, was investigated by Anomalous Small Angle X-ray scattering (ASAXS) and Wide-Angle X-Ray Scattering WAXS techniques. The hydrolysis and condensation of 3-aminopropyltrimethoxysilane or zirconium tetrapropylate in this polymeric matrix were used to produce poly(3-aminopropyl silsesquioxane) or ZrO2, as nanofillers. Contrary to previous results reported for membranes containing phosphomolybdic acid, the PTA could be completely dissolved in the SPEEK matrix. The applicability of the Guinier approximation for the SPEEK/PTA membrane confirmed that the PTA was dispersed as isolated nanoparticles. The incorporation of poly(3-aminopropyl silsesquioxane) in the SPEEK/PTA system caused the agglomeration of the heteropolyacid as 30 nm large particles. The ZrO2 had little effect on the distribution of PTA in the SPEEK matrix. On the other hand, no crystallization of the heteropolyacid was observed in the membranes.

KW - Diffraction and scattering measurements

KW - Nanoparticles, colloids and quantum structures

KW - Organic-inorganic hybrids

KW - Polymers and organics

KW - X-ray diffraction

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U2 - 10.1016/j.jnoncrysol.2008.09.036

DO - 10.1016/j.jnoncrysol.2008.09.036

M3 - Article

AN - SCOPUS:58049127565

SN - 0022-3093

VL - 355

SP - 6

EP - 11

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 1

ER -

Analysis of proton-conducting organic-inorganic hybrid materials based on sulphonated poly(ether ether ketone) and phosphotungstic acid via ASAXS and WAXS

Abstract

Keywords

ASJC Scopus subject areas

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