Assembly of two metal-organic frameworks with intrinsic chiral topology from achiral materials

Xuemin Jing; Lirong Zhang; Ma Tianliang; Guanghua Li; Yang Yu; Qisheng Huo; Mohamed Eddaoudi; Yunling Liu

doi:10.1021/cg9015096

Assembly of two metal-organic frameworks with intrinsic chiral topology from achiral materials

Xuemin Jing, Lirong Zhang, Ma Tianliang, Guanghua Li, Yang Yu, Qisheng Huo, Mohamed Eddaoudi, Yunling Liu^*

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

76 Scopus citations

Abstract

The assembly of Cu(CH₃COO)₂·H₂O and pyridine-4,5-imidazoledicarboxylic acid (H₃PyImDC) under solvothermal conditions in the presence of different organic templates yielded two three-dimensional chiral frameworks, (C₃H₁₀N ₂)(C₃H₇NO)_0.5- (H₂O) ₂[Cu^IIC₁₀H₅O₄N ₃] (1) and |(C₄H₉NO)_0.5(H ₂O)₈[Cu^II₂Cu^I(C ₁₀H₅O₄N₃)₂(C ₁₀H₆O₄N₃)] (2). Both of the compounds crystallized in the cubic, P4₃32 space group and possessed open helical channels in the frameworks. To the best of our knowledge, compounds 1 and 2 present the first synthesized MOFs with a bmn and lcy-a net. Further characterization of the two compounds has been performed, including X-ray powder diffraction, inductively coupled plasma analysis, CHN, IR spectra, fluorescence spectra, X-ray photoelectron spectroscopy spectrum and thermogravimetric- differential thermal analysis.

Original language	English (US)
Pages (from-to)	492-494
Number of pages	3
Journal	Crystal Growth and Design
Volume	10
Issue number	2
DOIs	https://doi.org/10.1021/cg9015096
State	Published - Feb 3 2010

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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@article{316e8784ced8490db9d205b41930f2e1,

title = "Assembly of two metal-organic frameworks with intrinsic chiral topology from achiral materials",

abstract = "The assembly of Cu(CH3COO)2·H2O and pyridine-4,5-imidazoledicarboxylic acid (H3PyImDC) under solvothermal conditions in the presence of different organic templates yielded two three-dimensional chiral frameworks, (C3H10N 2)(C3H7NO)0.5- (H2O) 2[CuIIC10H5O4N 3] (1) and |(C4H9NO)0.5(H 2O)8[CuII2CuI(C 10H5O4N3)2(C 10H6O4N3)] (2). Both of the compounds crystallized in the cubic, P4332 space group and possessed open helical channels in the frameworks. To the best of our knowledge, compounds 1 and 2 present the first synthesized MOFs with a bmn and lcy-a net. Further characterization of the two compounds has been performed, including X-ray powder diffraction, inductively coupled plasma analysis, CHN, IR spectra, fluorescence spectra, X-ray photoelectron spectroscopy spectrum and thermogravimetric- differential thermal analysis.",

author = "Xuemin Jing and Lirong Zhang and Ma Tianliang and Guanghua Li and Yang Yu and Qisheng Huo and Mohamed Eddaoudi and Yunling Liu",

year = "2010",

month = feb,

day = "3",

doi = "10.1021/cg9015096",

language = "English (US)",

volume = "10",

pages = "492--494",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "2",

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TY - JOUR

T1 - Assembly of two metal-organic frameworks with intrinsic chiral topology from achiral materials

AU - Jing, Xuemin

AU - Zhang, Lirong

AU - Tianliang, Ma

AU - Li, Guanghua

AU - Yu, Yang

AU - Huo, Qisheng

AU - Eddaoudi, Mohamed

AU - Liu, Yunling

PY - 2010/2/3

Y1 - 2010/2/3

N2 - The assembly of Cu(CH3COO)2·H2O and pyridine-4,5-imidazoledicarboxylic acid (H3PyImDC) under solvothermal conditions in the presence of different organic templates yielded two three-dimensional chiral frameworks, (C3H10N 2)(C3H7NO)0.5- (H2O) 2[CuIIC10H5O4N 3] (1) and |(C4H9NO)0.5(H 2O)8[CuII2CuI(C 10H5O4N3)2(C 10H6O4N3)] (2). Both of the compounds crystallized in the cubic, P4332 space group and possessed open helical channels in the frameworks. To the best of our knowledge, compounds 1 and 2 present the first synthesized MOFs with a bmn and lcy-a net. Further characterization of the two compounds has been performed, including X-ray powder diffraction, inductively coupled plasma analysis, CHN, IR spectra, fluorescence spectra, X-ray photoelectron spectroscopy spectrum and thermogravimetric- differential thermal analysis.

AB - The assembly of Cu(CH3COO)2·H2O and pyridine-4,5-imidazoledicarboxylic acid (H3PyImDC) under solvothermal conditions in the presence of different organic templates yielded two three-dimensional chiral frameworks, (C3H10N 2)(C3H7NO)0.5- (H2O) 2[CuIIC10H5O4N 3] (1) and |(C4H9NO)0.5(H 2O)8[CuII2CuI(C 10H5O4N3)2(C 10H6O4N3)] (2). Both of the compounds crystallized in the cubic, P4332 space group and possessed open helical channels in the frameworks. To the best of our knowledge, compounds 1 and 2 present the first synthesized MOFs with a bmn and lcy-a net. Further characterization of the two compounds has been performed, including X-ray powder diffraction, inductively coupled plasma analysis, CHN, IR spectra, fluorescence spectra, X-ray photoelectron spectroscopy spectrum and thermogravimetric- differential thermal analysis.

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U2 - 10.1021/cg9015096

DO - 10.1021/cg9015096

M3 - Article

AN - SCOPUS:76349113163

SN - 1528-7483

VL - 10

SP - 492

EP - 494

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 2

ER -

Assembly of two metal-organic frameworks with intrinsic chiral topology from achiral materials

Abstract

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