TY - JOUR
T1 - Asymmetric Brønsted Acid Catalyzed Substitution of Diaryl Methanols with Thiols and Alcohols for the Synthesis of Chiral Thioethers and Ethers
AU - Chatupheeraphat, Adisak
AU - Liao, Hsuan-Hung
AU - Mader, Steffen
AU - Sako, Makoto
AU - Sasai, Hiroaki
AU - Atodiresei, Iuliana
AU - Rueping, Magnus
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: S.M. thanks the DFG (Deutsche Forschungsgemeinschaft) for financial support through the International Research Training Group SeleCa (IRTG 1628), H.-H.L. thanks the DAAD for a doctoral fellowship, M.S. thanks the JSPS (Japanese Society for the Promotion of Science) for financial support through the Japanese-German Graduate Externship.
PY - 2016/3/8
Y1 - 2016/3/8
N2 - An enantioselective addition of thiols and alcohols to aza-ortho-quinone methides, starting from diaryl methanols, was developed. The asymmetric additions occur under mild reaction conditions in the presence of chiral phosphoric acids and furnish the corresponding adducts with excellent yields and enantioselectivities.
AB - An enantioselective addition of thiols and alcohols to aza-ortho-quinone methides, starting from diaryl methanols, was developed. The asymmetric additions occur under mild reaction conditions in the presence of chiral phosphoric acids and furnish the corresponding adducts with excellent yields and enantioselectivities.
UR - http://hdl.handle.net/10754/623140
UR - http://doi.wiley.com/10.1002/anie.201511179
UR - http://www.scopus.com/inward/record.url?scp=84960145514&partnerID=8YFLogxK
U2 - 10.1002/anie.201511179
DO - 10.1002/anie.201511179
M3 - Article
C2 - 26952288
SN - 1433-7851
VL - 55
SP - 4803
EP - 4807
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
IS - 15
ER -