Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations

Magnus Rueping; Henrik Sundén; Lukas Hubener; Erli Sugiono

doi:10.1039/c2cc16447g

Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations

Magnus Rueping^*, Henrik Sundén, Lukas Hubener, Erli Sugiono

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

91 Scopus citations

Abstract

Enantioselective oxidative domino reactions of allylic alcohols to functionalized aldehydes have been developed. The one pot domino oxidation-iminium activation represents a convenient strategy for the enantioselective addition of malonates to allylic alcohols and the asymmetric formation of formyl cyclopropanes.

Original language	English (US)
Pages (from-to)	2201-2203
Number of pages	3
Journal	CHEMICAL COMMUNICATIONS
Volume	48
Issue number	16
DOIs	https://doi.org/10.1039/c2cc16447g
State	Published - Jan 26 2012
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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title = "Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations",

abstract = "Enantioselective oxidative domino reactions of allylic alcohols to functionalized aldehydes have been developed. The one pot domino oxidation-iminium activation represents a convenient strategy for the enantioselective addition of malonates to allylic alcohols and the asymmetric formation of formyl cyclopropanes.",

author = "Magnus Rueping and Henrik Sund{\'e}n and Lukas Hubener and Erli Sugiono",

year = "2012",

month = jan,

day = "26",

doi = "10.1039/c2cc16447g",

language = "English (US)",

volume = "48",

pages = "2201--2203",

journal = "CHEMICAL COMMUNICATIONS",

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publisher = "ROYAL SOC CHEMISTRY",

number = "16",

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T1 - Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations

AU - Rueping, Magnus

AU - Sundén, Henrik

AU - Hubener, Lukas

AU - Sugiono, Erli

PY - 2012/1/26

Y1 - 2012/1/26

N2 - Enantioselective oxidative domino reactions of allylic alcohols to functionalized aldehydes have been developed. The one pot domino oxidation-iminium activation represents a convenient strategy for the enantioselective addition of malonates to allylic alcohols and the asymmetric formation of formyl cyclopropanes.

AB - Enantioselective oxidative domino reactions of allylic alcohols to functionalized aldehydes have been developed. The one pot domino oxidation-iminium activation represents a convenient strategy for the enantioselective addition of malonates to allylic alcohols and the asymmetric formation of formyl cyclopropanes.

UR - http://www.scopus.com/inward/record.url?scp=84856508633&partnerID=8YFLogxK

U2 - 10.1039/c2cc16447g

DO - 10.1039/c2cc16447g

M3 - Article

C2 - 22252220

AN - SCOPUS:84856508633

SN - 1359-7345

VL - 48

SP - 2201

EP - 2203

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 16

ER -

Asymmetric oxidative Lewis base catalysis—unifying iminium and enamine organocatalysis with oxidations

Abstract

ASJC Scopus subject areas

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