Base-induced solvent switches in acid-base reactions

Omar F. Mohammed; Dina Pines; Erik T.J. Nibbering; Ehud Pines

doi:10.1002/anie.200603383

Base-induced solvent switches in acid-base reactions

Omar F. Mohammed^*, Dina Pines, Erik T.J. Nibbering, Ehud Pines

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

204 Scopus citations

Abstract

(Figure Presented) Fast switches: Eigen and Weller's classic diffusion reaction model for aqueous acid-base neutralization reactions is used to interpret the proton-transfer dynamics between pyranine and trichloroacetate. Upon mutual diffusion of the acid and base to form an encounter reaction complex, solvent switches mediate the proton transfer between acid and base and provide a general framework for all observed dynamic features (see picture; ROH = acid, B = base).

Original language	English (US)
Pages (from-to)	1458-1461
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	9
DOIs	https://doi.org/10.1002/anie.200603383
State	Published - 2007
Externally published	Yes

Keywords

Basicity
Femtochemistry
Ion pairs
Proton transfer
Reaction mechanisms

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200603383

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title = "Base-induced solvent switches in acid-base reactions",

abstract = "(Figure Presented) Fast switches: Eigen and Weller's classic diffusion reaction model for aqueous acid-base neutralization reactions is used to interpret the proton-transfer dynamics between pyranine and trichloroacetate. Upon mutual diffusion of the acid and base to form an encounter reaction complex, solvent switches mediate the proton transfer between acid and base and provide a general framework for all observed dynamic features (see picture; ROH = acid, B = base).",

keywords = "Basicity, Femtochemistry, Ion pairs, Proton transfer, Reaction mechanisms",

author = "Mohammed, {Omar F.} and Dina Pines and Nibbering, {Erik T.J.} and Ehud Pines",

year = "2007",

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journal = "Angewandte Chemie - International Edition",

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AU - Mohammed, Omar F.

AU - Pines, Dina

AU - Nibbering, Erik T.J.

AU - Pines, Ehud

PY - 2007

Y1 - 2007

N2 - (Figure Presented) Fast switches: Eigen and Weller's classic diffusion reaction model for aqueous acid-base neutralization reactions is used to interpret the proton-transfer dynamics between pyranine and trichloroacetate. Upon mutual diffusion of the acid and base to form an encounter reaction complex, solvent switches mediate the proton transfer between acid and base and provide a general framework for all observed dynamic features (see picture; ROH = acid, B = base).

AB - (Figure Presented) Fast switches: Eigen and Weller's classic diffusion reaction model for aqueous acid-base neutralization reactions is used to interpret the proton-transfer dynamics between pyranine and trichloroacetate. Upon mutual diffusion of the acid and base to form an encounter reaction complex, solvent switches mediate the proton transfer between acid and base and provide a general framework for all observed dynamic features (see picture; ROH = acid, B = base).

KW - Basicity

KW - Femtochemistry

KW - Ion pairs

KW - Proton transfer

KW - Reaction mechanisms

UR - http://www.scopus.com/inward/record.url?scp=33947198874&partnerID=8YFLogxK

U2 - 10.1002/anie.200603383

DO - 10.1002/anie.200603383

M3 - Article

C2 - 17212371

AN - SCOPUS:33947198874

SN - 1433-7851

VL - 46

SP - 1458

EP - 1461

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Base-induced solvent switches in acid-base reactions

Abstract

Keywords

ASJC Scopus subject areas

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