Benzene-fused BODIPYs: Synthesis and the impact of fusion mode

Yong Ni; Wangdong Zeng; Kuo-Wei Huang; Jishan Wu

doi:10.1039/c2cc38380b

Benzene-fused BODIPYs: Synthesis and the impact of fusion mode

Yong Ni, Wangdong Zeng, Kuo-Wei Huang, Jishan Wu

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96 Scopus citations

Abstract

BODIPY derivatives with one or two benzene units fused at different positions are prepared using novel synthetic methods. The resulting dye 1 shows deep red fluorescence with a large Stokes shift. Dyes 2 and 3 are reported for the first time and 3 exhibits near infrared absorption. The impact of benzannulation at different positions of BODIPY is discussed, and the geometry and electronic structure are studied by DFT calculations. This journal is © 2013 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	1217
Journal	Chemical Communications
Volume	49
Issue number	12
DOIs	https://doi.org/10.1039/c2cc38380b
State	Published - 2013

ASJC Scopus subject areas

Materials Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Ceramics and Composites
General Chemistry
Catalysis
Electronic, Optical and Magnetic Materials

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title = "Benzene-fused BODIPYs: Synthesis and the impact of fusion mode",

abstract = "BODIPY derivatives with one or two benzene units fused at different positions are prepared using novel synthetic methods. The resulting dye 1 shows deep red fluorescence with a large Stokes shift. Dyes 2 and 3 are reported for the first time and 3 exhibits near infrared absorption. The impact of benzannulation at different positions of BODIPY is discussed, and the geometry and electronic structure are studied by DFT calculations. This journal is {\textcopyright} 2013 The Royal Society of Chemistry.",

author = "Yong Ni and Wangdong Zeng and Kuo-Wei Huang and Jishan Wu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: J.W. acknowledges financial support from the SPORE (COY-15-EWI-RCFSA/N197-1), BMRC-NMRC grant (no. 10/1/21/19/642), and IMRE Core funding (IMRE/10-1P0509). K.-W.H. acknowledges financial support from KAUST.",

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doi = "10.1039/c2cc38380b",

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AU - Ni, Yong

AU - Zeng, Wangdong

AU - Huang, Kuo-Wei

AU - Wu, Jishan

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: J.W. acknowledges financial support from the SPORE (COY-15-EWI-RCFSA/N197-1), BMRC-NMRC grant (no. 10/1/21/19/642), and IMRE Core funding (IMRE/10-1P0509). K.-W.H. acknowledges financial support from KAUST.

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AB - BODIPY derivatives with one or two benzene units fused at different positions are prepared using novel synthetic methods. The resulting dye 1 shows deep red fluorescence with a large Stokes shift. Dyes 2 and 3 are reported for the first time and 3 exhibits near infrared absorption. The impact of benzannulation at different positions of BODIPY is discussed, and the geometry and electronic structure are studied by DFT calculations. This journal is © 2013 The Royal Society of Chemistry.

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Benzene-fused BODIPYs: Synthesis and the impact of fusion mode

Abstract

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