Bicompartmentalized polymer particles by tandem ROMP and ATRP in miniemulsion

Cédric Airaud; Valérie Héroguez; Yves Gnanou

doi:10.1021/ma702682s

Bicompartmentalized polymer particles by tandem ROMP and ATRP in miniemulsion

Cédric Airaud, Valérie Héroguez^*, Yves Gnanou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

This study describes an original approach to prepare biphasic particles by simultaneous ringopening metathesis polymerization (ROMP) of norbornene and atom-transfer radical polymerization (ATRP) of methyl methacrylate under miniemulsion conditions. A single water-soluble ruthenium macrocatalyst was used to initiate ROMP and mediate ATRP. All situations led to high conversions, and well-distributed particles containing two incompatible homopolymers grown under controlled conditions could indeed be prepared.

Original language	English (US)
Pages (from-to)	3015-3022
Number of pages	8
Journal	Macromolecules
Volume	41
Issue number	9
DOIs	https://doi.org/10.1021/ma702682s
State	Published - May 13 2008
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma702682s

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abstract = "This study describes an original approach to prepare biphasic particles by simultaneous ringopening metathesis polymerization (ROMP) of norbornene and atom-transfer radical polymerization (ATRP) of methyl methacrylate under miniemulsion conditions. A single water-soluble ruthenium macrocatalyst was used to initiate ROMP and mediate ATRP. All situations led to high conversions, and well-distributed particles containing two incompatible homopolymers grown under controlled conditions could indeed be prepared.",

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AU - Héroguez, Valérie

AU - Gnanou, Yves

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Y1 - 2008/5/13

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AB - This study describes an original approach to prepare biphasic particles by simultaneous ringopening metathesis polymerization (ROMP) of norbornene and atom-transfer radical polymerization (ATRP) of methyl methacrylate under miniemulsion conditions. A single water-soluble ruthenium macrocatalyst was used to initiate ROMP and mediate ATRP. All situations led to high conversions, and well-distributed particles containing two incompatible homopolymers grown under controlled conditions could indeed be prepared.

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Bicompartmentalized polymer particles by tandem ROMP and ATRP in miniemulsion

Abstract

ASJC Scopus subject areas

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