Bisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistors

Chenhua Tong; Jingjing Chang; Junmin Tan; Gaole Dai; Kuo-Wei Huang; Hardysze Chan; Chunyan Chi

doi:10.1039/c3ob40982a

Bisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistors

Chenhua Tong, Jingjing Chang, Junmin Tan, Gaole Dai, Kuo-Wei Huang, Hardysze Chan, Chunyan Chi

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Several bisacenaphthopyrazinoquinoxaline (BAPQ) based derivatives 1-3 were synthesized by condensation between the acenaphthenequinones and 1,2,4,5-tetraaminobenzene tetrahydrochloride. Their optical, electrochemical and self-assembling properties are tuned by different substituents. Among them, compound 3 possesses a homogeneously distributed low-lying LUMO due to the peripheral substitution with four cyano groups. The corresponding n-channel field effect transistors showed a field effect electron mobility of 5 × 10-3 cm2 V-1 s-1. © 2013 The Royal Society of Chemistry.

Original language	English (US)
Pages (from-to)	5683
Journal	Organic and Biomolecular Chemistry
Volume	11
Issue number	34
DOIs	https://doi.org/10.1039/c3ob40982a
State	Published - 2013

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Physical and Theoretical Chemistry

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title = "Bisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistors",

abstract = "Several bisacenaphthopyrazinoquinoxaline (BAPQ) based derivatives 1-3 were synthesized by condensation between the acenaphthenequinones and 1,2,4,5-tetraaminobenzene tetrahydrochloride. Their optical, electrochemical and self-assembling properties are tuned by different substituents. Among them, compound 3 possesses a homogeneously distributed low-lying LUMO due to the peripheral substitution with four cyano groups. The corresponding n-channel field effect transistors showed a field effect electron mobility of 5 × 10-3 cm2 V-1 s-1. {\textcopyright} 2013 The Royal Society of Chemistry.",

author = "Chenhua Tong and Jingjing Chang and Junmin Tan and Gaole Dai and Kuo-Wei Huang and Hardysze Chan and Chunyan Chi",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was financially supported by the Singapore MOE AcRF grants R-143-000-510-112 and NUS Start Up grant R-143-000-486-133 (C. C.) and KAUST (K.-W. H.).",

year = "2013",

doi = "10.1039/c3ob40982a",

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TY - JOUR

T1 - Bisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistors

AU - Tong, Chenhua

AU - Chang, Jingjing

AU - Tan, Junmin

AU - Dai, Gaole

AU - Huang, Kuo-Wei

AU - Chan, Hardysze

AU - Chi, Chunyan

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was financially supported by the Singapore MOE AcRF grants R-143-000-510-112 and NUS Start Up grant R-143-000-486-133 (C. C.) and KAUST (K.-W. H.).

PY - 2013

Y1 - 2013

N2 - Several bisacenaphthopyrazinoquinoxaline (BAPQ) based derivatives 1-3 were synthesized by condensation between the acenaphthenequinones and 1,2,4,5-tetraaminobenzene tetrahydrochloride. Their optical, electrochemical and self-assembling properties are tuned by different substituents. Among them, compound 3 possesses a homogeneously distributed low-lying LUMO due to the peripheral substitution with four cyano groups. The corresponding n-channel field effect transistors showed a field effect electron mobility of 5 × 10-3 cm2 V-1 s-1. © 2013 The Royal Society of Chemistry.

AB - Several bisacenaphthopyrazinoquinoxaline (BAPQ) based derivatives 1-3 were synthesized by condensation between the acenaphthenequinones and 1,2,4,5-tetraaminobenzene tetrahydrochloride. Their optical, electrochemical and self-assembling properties are tuned by different substituents. Among them, compound 3 possesses a homogeneously distributed low-lying LUMO due to the peripheral substitution with four cyano groups. The corresponding n-channel field effect transistors showed a field effect electron mobility of 5 × 10-3 cm2 V-1 s-1. © 2013 The Royal Society of Chemistry.

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U2 - 10.1039/c3ob40982a

DO - 10.1039/c3ob40982a

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SN - 1477-0520

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SP - 5683

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 34

ER -

Bisacenaphthopyrazinoquinoxaline derivatives: Synthesis, physical properties and applications as semiconductors for n-channel field effect transistors

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