Bis[tris-(2-ammonio-ethyl)amine] bis-(penta-fluoridooxidomolybdate) difluoride monohydrate

K. Adil; J. Marrot; M. Leblanc; V. Maisonneuve

doi:10.1107/S1600536807018077

Bis[tris-(2-ammonio-ethyl)amine] bis-(penta-fluoridooxidomolybdate) difluoride monohydrate

K. Adil, J. Marrot, M. Leblanc, V. Maisonneuve^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The first fluoridooxidomolybdate of tris-(2-amino-ethyl)amine (tren), bis-[tris-(2-ammonio-ethyl)amine] bis-(penta-fluorido-oxido-molybdate) difluoride monohydrate, (C6H21N4)2[MoOF5]2F2·H2O, was obtained by solvothermal synthesis using microwave heating from the reaction of molybdenum oxide, tris-2-(aminoethyl)amine, aqueous HF and ethanol at 463 K for 1 h. The structure consists of [MoOF5]^2- octa-hedra, isolated fluoride ions, water mol-ecules and triprotonated tren cations. Cohesion is ensured by a network of hydrogen bonds.

Original language	English (US)
Pages (from-to)	m1511-m1513
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	5
DOIs	https://doi.org/10.1107/S1600536807018077
State	Published - 2007
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Bis[tris-(2-ammonio-ethyl)amine] bis-(penta-fluoridooxidomolybdate) difluoride monohydrate",

abstract = "The first fluoridooxidomolybdate of tris-(2-amino-ethyl)amine (tren), bis-[tris-(2-ammonio-ethyl)amine] bis-(penta-fluorido-oxido-molybdate) difluoride monohydrate, (C6H21N4)2[MoOF5]2F2·H2O, was obtained by solvothermal synthesis using microwave heating from the reaction of molybdenum oxide, tris-2-(aminoethyl)amine, aqueous HF and ethanol at 463 K for 1 h. The structure consists of [MoOF5]2- octa-hedra, isolated fluoride ions, water mol-ecules and triprotonated tren cations. Cohesion is ensured by a network of hydrogen bonds.",

author = "K. Adil and J. Marrot and M. Leblanc and V. Maisonneuve",

year = "2007",

doi = "10.1107/S1600536807018077",

language = "English (US)",

volume = "63",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Bis[tris-(2-ammonio-ethyl)amine] bis-(penta-fluoridooxidomolybdate) difluoride monohydrate

AU - Adil, K.

AU - Marrot, J.

AU - Leblanc, M.

AU - Maisonneuve, V.

PY - 2007

Y1 - 2007

N2 - The first fluoridooxidomolybdate of tris-(2-amino-ethyl)amine (tren), bis-[tris-(2-ammonio-ethyl)amine] bis-(penta-fluorido-oxido-molybdate) difluoride monohydrate, (C6H21N4)2[MoOF5]2F2·H2O, was obtained by solvothermal synthesis using microwave heating from the reaction of molybdenum oxide, tris-2-(aminoethyl)amine, aqueous HF and ethanol at 463 K for 1 h. The structure consists of [MoOF5]2- octa-hedra, isolated fluoride ions, water mol-ecules and triprotonated tren cations. Cohesion is ensured by a network of hydrogen bonds.

AB - The first fluoridooxidomolybdate of tris-(2-amino-ethyl)amine (tren), bis-[tris-(2-ammonio-ethyl)amine] bis-(penta-fluorido-oxido-molybdate) difluoride monohydrate, (C6H21N4)2[MoOF5]2F2·H2O, was obtained by solvothermal synthesis using microwave heating from the reaction of molybdenum oxide, tris-2-(aminoethyl)amine, aqueous HF and ethanol at 463 K for 1 h. The structure consists of [MoOF5]2- octa-hedra, isolated fluoride ions, water mol-ecules and triprotonated tren cations. Cohesion is ensured by a network of hydrogen bonds.

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DO - 10.1107/S1600536807018077

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JO - Acta Crystallographica Section E: Structure Reports Online

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Bis[tris-(2-ammonio-ethyl)amine] bis-(penta-fluoridooxidomolybdate) difluoride monohydrate

Abstract

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