TY - JOUR
T1 - Bis[tris-(2-ammonio-ethyl)amine] bis-(penta-fluoridooxidomolybdate) difluoride monohydrate
AU - Adil, Karim
AU - Marrot, J.
AU - Leblanc, M.
AU - Maisonneuve, V.
PY - 2007/1/1
Y1 - 2007/1/1
N2 - The first fluoridooxidomolybdate of tris-(2-amino-ethyl)amine (tren), bis-[tris-(2-ammonio-ethyl)amine] bis-(penta-fluorido-oxido-molybdate) difluoride monohydrate, (C6H21N4)2[MoOF5]2F2·H2O, was obtained by solvothermal synthesis using microwave heating from the reaction of molybdenum oxide, tris-2-(aminoethyl)amine, aqueous HF and ethanol at 463 K for 1 h. The structure consists of [MoOF5]2- octa-hedra, isolated fluoride ions, water mol-ecules and triprotonated tren cations. Cohesion is ensured by a network of hydrogen bonds.
AB - The first fluoridooxidomolybdate of tris-(2-amino-ethyl)amine (tren), bis-[tris-(2-ammonio-ethyl)amine] bis-(penta-fluorido-oxido-molybdate) difluoride monohydrate, (C6H21N4)2[MoOF5]2F2·H2O, was obtained by solvothermal synthesis using microwave heating from the reaction of molybdenum oxide, tris-2-(aminoethyl)amine, aqueous HF and ethanol at 463 K for 1 h. The structure consists of [MoOF5]2- octa-hedra, isolated fluoride ions, water mol-ecules and triprotonated tren cations. Cohesion is ensured by a network of hydrogen bonds.
UR - http://www.scopus.com/inward/record.url?scp=57349095268&partnerID=8YFLogxK
U2 - 10.1107/S1600536807018077
DO - 10.1107/S1600536807018077
M3 - Article
AN - SCOPUS:57349095268
SN - 1600-5368
VL - 63
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 5
ER -