Abstract
The reaction of Cp*ZrMe3, 1, with the heterogeneous activator [≡SiO-B(C6F5)3]−[HNEt2Ph]+, 2, has been investigated to generate, by an irreversible process of methane elimination, the well-defined cationic silica-supported metallocenium species [≡SiO-B(C6F5)3]−[Cp*ZrMe2(NEt2Ph)]+, 3, as an active olefin polymerisation catalyst.
Original language | English (US) |
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Pages (from-to) | 2034-2035 |
Number of pages | 2 |
Journal | CHEMICAL COMMUNICATIONS |
Volume | 3 |
Issue number | 16 |
DOIs | |
State | Published - 2003 |
Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry