TY - JOUR
T1 - Carbon dioxide selective adsorption within a highly stable mixed-ligand Zeolitic Imidazolate Framework
AU - Huang, Lin
AU - Xue, Ming
AU - Song, Qingshan
AU - Chen, Siru
AU - Pan, Ying
AU - Qiu, Shilun
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledged KAUST grant number(s): CRG-1-2012-LAI-009
Acknowledgements: This work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21101072, 21261130584, 91022030), "111" project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).
This publication acknowledges KAUST support, but has no KAUST affiliated authors.
PY - 2014/8
Y1 - 2014/8
N2 - A new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. © 2014 Elsevier B.V.
AB - A new mixed-ligand Zeolitic Imidazolate Framework Zn4(2-mbIm) 3(bIm)5·4H2O (named JUC-160, 2-mbIm = 2-methylbenzimidazole, bIm = benzimidazole and JUC = Jilin University China) was synthesized with a solvothermal reaction of Zn(NO3) 2·6H2O, bIm and 2-mbIm in DMF solution at 180 °C. Topological analysis indicated that JUC-160 has a zeolite GIS (gismondine) topology. Study of the gas adsorption and thermal and chemical stability of JUC-160 demonstrated its selective adsorption property for carbon dioxide, high thermal stability, and remarkable chemical resistance to boiling alkaline water and organic solvent for up to one week. © 2014 Elsevier B.V.
UR - http://hdl.handle.net/10754/597728
UR - https://linkinghub.elsevier.com/retrieve/pii/S138770031400197X
UR - http://www.scopus.com/inward/record.url?scp=84901260597&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2014.04.026
DO - 10.1016/j.inoche.2014.04.026
M3 - Article
SN - 1387-7003
VL - 46
SP - 9
EP - 12
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -