Carbonization of covalent triazine-based frameworks: Via ionic liquid induction

Jiangtao Jia; Zhijie Chen; Youssef Belmabkhout; Karim Adil; Prashant M. Bhatt; Vera A. Solovyeva; Osama Shekhah; Mohamed Eddaoudi

doi:10.1039/c8ta05583a

Carbonization of covalent triazine-based frameworks: Via ionic liquid induction

Jiangtao Jia, Zhijie Chen, Youssef Belmabkhout, Karim Adil, Prashant M. Bhatt, Vera A. Solovyeva, Osama Shekhah, Mohamed Eddaoudi^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl₂ as an ionic liquid were allowed to alter/enhance the Brunauer-Emmett-Teller (BET) surface areas of the POPs in the range from 760 to 1560 m² g^-1. The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.

Original language	English (US)
Pages (from-to)	15564-15568
Number of pages	5
Journal	JOURNAL OF MATERIALS CHEMISTRY A
Volume	6
Issue number	32
DOIs	https://doi.org/10.1039/c8ta05583a
State	Published - 2018

ASJC Scopus subject areas

General Chemistry
Renewable Energy, Sustainability and the Environment
General Materials Science

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title = "Carbonization of covalent triazine-based frameworks: Via ionic liquid induction",

abstract = "A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl2 as an ionic liquid were allowed to alter/enhance the Brunauer-Emmett-Teller (BET) surface areas of the POPs in the range from 760 to 1560 m2 g-1. The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.",

author = "Jiangtao Jia and Zhijie Chen and Youssef Belmabkhout and Karim Adil and Bhatt, {Prashant M.} and Solovyeva, {Vera A.} and Osama Shekhah and Mohamed Eddaoudi",

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volume = "6",

pages = "15564--15568",

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TY - JOUR

T1 - Carbonization of covalent triazine-based frameworks

T2 - Via ionic liquid induction

AU - Jia, Jiangtao

AU - Chen, Zhijie

AU - Belmabkhout, Youssef

AU - Adil, Karim

AU - Bhatt, Prashant M.

AU - Solovyeva, Vera A.

AU - Shekhah, Osama

AU - Eddaoudi, Mohamed

PY - 2018

Y1 - 2018

N2 - A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl2 as an ionic liquid were allowed to alter/enhance the Brunauer-Emmett-Teller (BET) surface areas of the POPs in the range from 760 to 1560 m2 g-1. The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.

AB - A series of porous organic polymers (POPs) were synthesized using tetrahedral 1,3,5,7-tetracyanoadamantane as the main building block. The POP frameworks in the presence of different amounts of molten ZnCl2 as an ionic liquid were allowed to alter/enhance the Brunauer-Emmett-Teller (BET) surface areas of the POPs in the range from 760 to 1560 m2 g-1. The mechanism of the carbonization was unveiled by IR, EA and solid-state NMR; which is in situ ionic liquid induced polymerization and carbonization of the POPs.

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DO - 10.1039/c8ta05583a

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VL - 6

SP - 15564

EP - 15568

JO - JOURNAL OF MATERIALS CHEMISTRY A

JF - JOURNAL OF MATERIALS CHEMISTRY A

IS - 32

ER -

Carbonization of covalent triazine-based frameworks: Via ionic liquid induction

Abstract

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