TY - JOUR
T1 - Catalysis of silica-based anode (de-)lithiation: Compositional design within a hollow structure for accelerated conversion reaction kinetics
AU - Shen, Yabin
AU - Cao, Zhen
AU - Wu, Yingqiang
AU - Cheng, Yong
AU - Xue, Hongjin
AU - Zou, Yeguo
AU - Liu, Gang
AU - Yin, Dongming
AU - Cavallo, Luigi
AU - Wang, Limin
AU - Ming, Jun
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work is supported by the National Natural Science Foundation of China (21978281, 21975250) and the National Key R&D Program of China (SQ2017YFGH001474). The authors also thank the Independent Research Project of the State Key Laboratory of Rare Earth Resources Utilization (110005R086), Changchun Institute of Applied Chemistry, Chinese Academy of Sciences.
PY - 2020/6/2
Y1 - 2020/6/2
N2 - New hierarchical hollow SiO2 spheres (HHSs) decorated with metal nanoparticles (i.e., Co, Co-HHS) were designed using an in situ self-assembly approach. The Co nanoparticles were found to have a catalytic effect on (de-)lithiation of SiO2 and hence in storing lithium. Then, an extremely high capacity of 932 mA h g-1 and good cycling stability for more than 1000 cycles were demonstrated in the corresponding lithium battery. In addition, the lithium-ion full batteries of the Co-HHS versus lithium layered oxide cathode (e.g., LiNi1/3Co1/3Mn1/3O2, NCM333) were introduced and showed good performance, demonstrating the promising application of the Co-HHS, in particular for pursuing high-energy-density batteries. This journal is
AB - New hierarchical hollow SiO2 spheres (HHSs) decorated with metal nanoparticles (i.e., Co, Co-HHS) were designed using an in situ self-assembly approach. The Co nanoparticles were found to have a catalytic effect on (de-)lithiation of SiO2 and hence in storing lithium. Then, an extremely high capacity of 932 mA h g-1 and good cycling stability for more than 1000 cycles were demonstrated in the corresponding lithium battery. In addition, the lithium-ion full batteries of the Co-HHS versus lithium layered oxide cathode (e.g., LiNi1/3Co1/3Mn1/3O2, NCM333) were introduced and showed good performance, demonstrating the promising application of the Co-HHS, in particular for pursuing high-energy-density batteries. This journal is
UR - http://hdl.handle.net/10754/664317
UR - http://xlink.rsc.org/?DOI=D0TA01671C
UR - http://www.scopus.com/inward/record.url?scp=85087716246&partnerID=8YFLogxK
U2 - 10.1039/d0ta01671c
DO - 10.1039/d0ta01671c
M3 - Article
SN - 2050-7496
VL - 8
SP - 12306
EP - 12313
JO - Journal of Materials Chemistry A
JF - Journal of Materials Chemistry A
IS - 25
ER -