Catalytic asymmetric hydrogenation with the cluster Rh6(CO)10[(-)DIOP]3

R. Mutin; W. Abboud; J. M. Basset; D. Sinou

doi:10.1016/S0277-5387(00)87109-0

Catalytic asymmetric hydrogenation with the cluster Rh₆(CO)₁₀[(-)DIOP]₃

R. Mutin, W. Abboud, J. M. Basset^*, D. Sinou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Rh₆(CO)₁₀[(-)DIOP]₃ has been isolated after ligand exchange between Rh₆(CO)₁₆ and DIOP. The molecular cluster is an efficient catalyst for asymmetric reduction of various prochiral olefins; optical yields up to 47% have been achieved; the results are compared with those obtained with mononuclear rhodium (I) complexes.

Original language	English (US)
Pages (from-to)	539-541
Number of pages	3
Journal	Polyhedron
Volume	2
Issue number	6
DOIs	https://doi.org/10.1016/S0277-5387(00)87109-0
State	Published - 1983
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(00)87109-0

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@article{989b68726ab24f9da671a7116264333a,

title = "Catalytic asymmetric hydrogenation with the cluster Rh6(CO)10[(-)DIOP]3",

abstract = "Rh6(CO)10[(-)DIOP]3 has been isolated after ligand exchange between Rh6(CO)16 and DIOP. The molecular cluster is an efficient catalyst for asymmetric reduction of various prochiral olefins; optical yields up to 47% have been achieved; the results are compared with those obtained with mononuclear rhodium (I) complexes.",

author = "R. Mutin and W. Abboud and Basset, {J. M.} and D. Sinou",

year = "1983",

doi = "10.1016/S0277-5387(00)87109-0",

language = "English (US)",

volume = "2",

pages = "539--541",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

number = "6",

}

TY - JOUR

T1 - Catalytic asymmetric hydrogenation with the cluster Rh6(CO)10[(-)DIOP]3

AU - Mutin, R.

AU - Abboud, W.

AU - Basset, J. M.

AU - Sinou, D.

PY - 1983

Y1 - 1983

N2 - Rh6(CO)10[(-)DIOP]3 has been isolated after ligand exchange between Rh6(CO)16 and DIOP. The molecular cluster is an efficient catalyst for asymmetric reduction of various prochiral olefins; optical yields up to 47% have been achieved; the results are compared with those obtained with mononuclear rhodium (I) complexes.

AB - Rh6(CO)10[(-)DIOP]3 has been isolated after ligand exchange between Rh6(CO)16 and DIOP. The molecular cluster is an efficient catalyst for asymmetric reduction of various prochiral olefins; optical yields up to 47% have been achieved; the results are compared with those obtained with mononuclear rhodium (I) complexes.

UR - http://www.scopus.com/inward/record.url?scp=49049123654&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(00)87109-0

DO - 10.1016/S0277-5387(00)87109-0

M3 - Article

AN - SCOPUS:49049123654

SN - 0277-5387

VL - 2

SP - 539

EP - 541

JO - Polyhedron

JF - Polyhedron

IS - 6

ER -

Catalytic asymmetric hydrogenation with the cluster Rh₆(CO)₁₀[(-)DIOP]₃

Abstract

ASJC Scopus subject areas

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