Catalytic Intermolecular Cross-Couplings of Azides and LUMO-Activated Unsaturated Acyl Azoliums

Wenjun Li; Manjaly John Ajitha; Ming Lang; Kuo-Wei Huang; Jian Wang

doi:10.1021/acscatal.6b03674

Catalytic Intermolecular Cross-Couplings of Azides and LUMO-Activated Unsaturated Acyl Azoliums

Wenjun Li, Manjaly John Ajitha, Ming Lang, Kuo-Wei Huang, Jian Wang

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

An example for the catalytic synthesis of densely functionalized 1,2,3-triazoles through a LUMO activation mode has been developed. The protocol is enabled by intermolecular cross coupling reactions of azides with in situ-generated alpha,beta-unsaturated acyl azoliums. High yields and broad scope as well as the investigation of reaction mechanism are reported.

Original language	English (US)
Pages (from-to)	2139-2144
Number of pages	6
Journal	ACS Catalysis
Volume	7
Issue number	3
DOIs	https://doi.org/10.1021/acscatal.6b03674
State	Published - Feb 20 2017

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abstract = "An example for the catalytic synthesis of densely functionalized 1,2,3-triazoles through a LUMO activation mode has been developed. The protocol is enabled by intermolecular cross coupling reactions of azides with in situ-generated alpha,beta-unsaturated acyl azoliums. High yields and broad scope as well as the investigation of reaction mechanism are reported.",

author = "Wenjun Li and Ajitha, {Manjaly John} and Ming Lang and Kuo-Wei Huang and Jian Wang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Generous financial supports are provided by the National Natural Science Foundation of China (21672121, 21502043), the",

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AU - Li, Wenjun

AU - Ajitha, Manjaly John

AU - Lang, Ming

AU - Huang, Kuo-Wei

AU - Wang, Jian

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: Generous financial supports are provided by the National Natural Science Foundation of China (21672121, 21502043), the

PY - 2017/2/20

Y1 - 2017/2/20

N2 - An example for the catalytic synthesis of densely functionalized 1,2,3-triazoles through a LUMO activation mode has been developed. The protocol is enabled by intermolecular cross coupling reactions of azides with in situ-generated alpha,beta-unsaturated acyl azoliums. High yields and broad scope as well as the investigation of reaction mechanism are reported.

AB - An example for the catalytic synthesis of densely functionalized 1,2,3-triazoles through a LUMO activation mode has been developed. The protocol is enabled by intermolecular cross coupling reactions of azides with in situ-generated alpha,beta-unsaturated acyl azoliums. High yields and broad scope as well as the investigation of reaction mechanism are reported.

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UR - http://pubs.acs.org/doi/abs/10.1021/acscatal.6b03674

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JF - ACS Catalysis

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Catalytic Intermolecular Cross-Couplings of Azides and LUMO-Activated Unsaturated Acyl Azoliums

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