CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand

Fahran Ahmad Pasha; Anissa Bendjeriou-Sedjerari; Edy Abou-Hamad; Kuo-Wei Huang; Jean-Marie Basset

doi:10.1039/C5CC08821F

CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand

Fahran Ahmad Pasha, Anissa Bendjeriou-Sedjerari, Edy Abou-Hamad, Kuo-Wei Huang, Jean-Marie Basset

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.

Original language	English (US)
Pages (from-to)	2577-2580
Number of pages	4
Journal	Chem. Commun.
Volume	52
Issue number	12
DOIs	https://doi.org/10.1039/C5CC08821F
State	Published - 2016

Access to Document

10.1039/C5CC08821F

https://repository.kaust.edu.sa/bitstream/10754/593138/1/c5cc08821f.pdf

Cite this

@article{ea10e3e491e74e678161343e9483cbf4,

title = "CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand",

abstract = "Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.",

author = "Pasha, {Fahran Ahmad} and Anissa Bendjeriou-Sedjerari and Edy Abou-Hamad and Kuo-Wei Huang and Jean-Marie Basset",

note = "KAUST Repository Item: Exported on 2020-10-01",

year = "2016",

doi = "10.1039/C5CC08821F",

language = "English (US)",

volume = "52",

pages = "2577--2580",

journal = "Chem. Commun.",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand

AU - Pasha, Fahran Ahmad

AU - Bendjeriou-Sedjerari, Anissa

AU - Abou-Hamad, Edy

AU - Huang, Kuo-Wei

AU - Basset, Jean-Marie

N1 - KAUST Repository Item: Exported on 2020-10-01

PY - 2016

Y1 - 2016

N2 - Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.

AB - Density functional theory calculations and 2D 1H-13C HETCOR solid state NMR spectroscopy prove that CO2 can probe, by its own reactivity, different types of N-donor surface ligands on SBA15-supported ZrIV hydrides: [(≡Si-O-)(≡Si-N=)[Zr]H] and [(≡Si-NH-)(≡Si-X-)[Zr]H2] (X = O or NH). Moreover, [(≡Si-O-)(≡Si-N=)[Zr]H] activates CO2 more efficiently than the other complexes and leads to a carbimato Zr formate.

UR - http://hdl.handle.net/10754/593138

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C5CC08821F

UR - http://www.scopus.com/inward/record.url?scp=84957571834&partnerID=8YFLogxK

U2 - 10.1039/C5CC08821F

DO - 10.1039/C5CC08821F

M3 - Article

C2 - 26750777

SN - 1359-7345

VL - 52

SP - 2577

EP - 2580

JO - Chem. Commun.

JF - Chem. Commun.

IS - 12

ER -

CO2 activation through silylimido and silylamido zirconium hydrides supported on N-donor chelating SBA15 surface ligand

Abstract

Access to Document

Other files and links

Fingerprint

Cite this