Complex macromolecular architectures utilizing metallocene catalysts

Christos Batis, Giorgos Karanikolopoulos, Marinos Pitsikalis, Nikos Hadjichristidis*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

40 Scopus citations


Graft copolymers having poly(methyl methacrylate), PMMA, backbone and polystyrene, PS, polyisoprene, PI, poly(ethylene oxide), PEO, poly(2-methyl-1,3-pentadiene), P2MP, and PS-b-PI branches were prepared using the macromonomer methodology and high-vacuum techniques. The methacrylic macromonomers, mMM, were synthesized by anionic polymerization, whereas their homopolymerization and copolymerization with MMA were performed by metallocene catalyst. Relatively high macromonomer conversions were obtained in all cases. The parameters affecting the polymerization characteristics were examined. Well-defined poly(butyl methacrylate)-b-poly(methyl methacrylate) block copolymers were prepared for the first time by sequential addition of monomers starting from n-butyl methacrylate. The samples were characterized by size exclusion chromatography, SEC, 1H and 13C NMR spectroscopy, low-angle laser light scattering, LALLS, and differential scanning calorimetry, DSC.

Original languageEnglish (US)
Pages (from-to)9763-9774
Number of pages12
Issue number26
StatePublished - Dec 30 2003
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry


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