Abstract
This chapter summarizes recent developments on the synthesis of well-defined linear (multiblock co/terpolymer) as well as nonlinear (e.g. star, graft, block-graft, dendritic) complex macromolecular chimeras (polypeptide/polymer hybrids), by combining living/controlled polymerization methods of conventional monomers with the ring-opening polymerization of α-amino acid N-carboxyanhydrides. Although much development is still required, these complex polypeptide-based materials begin to rival their natural counterparts in terms of complexity and accuracy.
Original language | English (US) |
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Title of host publication | Complex Macromolecular Architectures |
Subtitle of host publication | Synthesis, Characterization, and Self-Assembly |
Publisher | John Wiley and Sons |
Pages | 461-489 |
Number of pages | 29 |
ISBN (Print) | 9780470825136 |
DOIs | |
State | Published - May 3 2011 |
Externally published | Yes |
Keywords
- Complex chimeras
- Controlled/living polymerization
- Dendritic chimeras
- Graft chimeras
- Living polymerization
- Macromolecular chimeras
- Multiblock chimeras
- Ring-opening polymerization
- Star chimeras
- α-amino acid N-carboxyanhydrides
ASJC Scopus subject areas
- General Chemistry