TY - JOUR
T1 - Continuous electrical pumping membrane process for seawater lithium mining
AU - Li, Zhen
AU - Li, Chunyang
AU - Liu, Xiaowei
AU - Cao, Li
AU - Li, Peipei
AU - Wei, Ruicong
AU - Li, Xiang
AU - Guo, Dong
AU - Huang, Kuo-Wei
AU - Lai, Zhiping
N1 - KAUST Repository Item: Exported on 2021-06-15
Acknowledged KAUST grant number(s): BAS/1/1375-01, URF/1/3769-01.
Acknowledgements: This work was financially supported by the KAUST baseline fund BAS/1/1375-01 and the KAUST competitive research fund URF/1/3769-01.
PY - 2021
Y1 - 2021
N2 - Seawater contains significantly larger quantities of lithium than is found on land, thereby providing an almost unlimited resource of lithium for meeting the rapid growth in demand for lithium batteries. However, lithium extraction from seawater is exceptionally challenging because of its low concentration (~0.1-0.2 ppm) and an abundance of interfering ions. Herein, we creatively employed a solid-state electrolyte membrane, and design a continuous electrically-driven membrane process, which successfully enriches lithium from seawater samples of the Red Sea by 43?000 times (i.e., from 0.21 to 9013.43 ppm) with a nominal Li/Mg selectivity >45 million. Lithium phosphate with a purity of 99.94% was precipitated directly from the enriched solution, thereby meeting the purity requirements for application in the lithium battery industry. Furthermore, a preliminary economic analysis shows that the process can be made profitable when coupled with the Chlor-alkali industry.
AB - Seawater contains significantly larger quantities of lithium than is found on land, thereby providing an almost unlimited resource of lithium for meeting the rapid growth in demand for lithium batteries. However, lithium extraction from seawater is exceptionally challenging because of its low concentration (~0.1-0.2 ppm) and an abundance of interfering ions. Herein, we creatively employed a solid-state electrolyte membrane, and design a continuous electrically-driven membrane process, which successfully enriches lithium from seawater samples of the Red Sea by 43?000 times (i.e., from 0.21 to 9013.43 ppm) with a nominal Li/Mg selectivity >45 million. Lithium phosphate with a purity of 99.94% was precipitated directly from the enriched solution, thereby meeting the purity requirements for application in the lithium battery industry. Furthermore, a preliminary economic analysis shows that the process can be made profitable when coupled with the Chlor-alkali industry.
UR - http://hdl.handle.net/10754/669575
UR - http://xlink.rsc.org/?DOI=D1EE00354B
UR - http://www.scopus.com/inward/record.url?scp=85107304831&partnerID=8YFLogxK
U2 - 10.1039/d1ee00354b
DO - 10.1039/d1ee00354b
M3 - Article
SN - 1754-5706
VL - 14
SP - 3152
EP - 3159
JO - Energy and Environmental Science
JF - Energy and Environmental Science
IS - 5
ER -