Controlled radical polymerization in the presence of β-phosphonylated nitroxide - Kinetics, mechanism and macromolecular architecture

Celine Chevalier; Sophie Robin; Didier Benoit; Olivier Guerret; Yves Gnanou

doi:10.14314/polimery.2003.499

Controlled radical polymerization in the presence of β-phosphonylated nitroxide - Kinetics, mechanism and macromolecular architecture

Celine Chevalier, Sophie Robin, Didier Benoit, Olivier Guerret, Yves Gnanou^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Using a newly designed N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide (DEPN), controlled radical polymerization of styrene and n-butyl acrylate, could be achieved. The rate constant of reversible deactivation of growing radicals by DEPN and the rate of dissociation of the alkoxyamine formed were determined. Miscellaneous macromolecular architectures, including block copolymers, stars and star block copolymers, were derived by this chemistry.

Original language	English (US)
Pages (from-to)	499-504
Number of pages	6
Journal	Polimery/Polymers
Volume	48
Issue number	7-8
DOIs	https://doi.org/10.14314/polimery.2003.499
State	Published - 2003
Externally published	Yes

Keywords

Block copolymers
Controlled radical polymerization
N-butyl acrylate
N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide
Star polymers
Styrene

ASJC Scopus subject areas

General Chemical Engineering
Polymers and Plastics
Materials Chemistry

Access to Document

10.14314/polimery.2003.499

Cite this

@article{603921e1578c40bd8e0c848427e7de62,

title = "Controlled radical polymerization in the presence of β-phosphonylated nitroxide - Kinetics, mechanism and macromolecular architecture",

abstract = "Using a newly designed N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide (DEPN), controlled radical polymerization of styrene and n-butyl acrylate, could be achieved. The rate constant of reversible deactivation of growing radicals by DEPN and the rate of dissociation of the alkoxyamine formed were determined. Miscellaneous macromolecular architectures, including block copolymers, stars and star block copolymers, were derived by this chemistry.",

keywords = "Block copolymers, Controlled radical polymerization, N-butyl acrylate, N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide, Star polymers, Styrene",

author = "Celine Chevalier and Sophie Robin and Didier Benoit and Olivier Guerret and Yves Gnanou",

year = "2003",

doi = "10.14314/polimery.2003.499",

language = "English (US)",

volume = "48",

pages = "499--504",

journal = "Polimery/Polymers",

issn = "0032-2725",

number = "7-8",

}

TY - JOUR

T1 - Controlled radical polymerization in the presence of β-phosphonylated nitroxide - Kinetics, mechanism and macromolecular architecture

AU - Chevalier, Celine

AU - Robin, Sophie

AU - Benoit, Didier

AU - Guerret, Olivier

AU - Gnanou, Yves

PY - 2003

Y1 - 2003

N2 - Using a newly designed N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide (DEPN), controlled radical polymerization of styrene and n-butyl acrylate, could be achieved. The rate constant of reversible deactivation of growing radicals by DEPN and the rate of dissociation of the alkoxyamine formed were determined. Miscellaneous macromolecular architectures, including block copolymers, stars and star block copolymers, were derived by this chemistry.

AB - Using a newly designed N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide (DEPN), controlled radical polymerization of styrene and n-butyl acrylate, could be achieved. The rate constant of reversible deactivation of growing radicals by DEPN and the rate of dissociation of the alkoxyamine formed were determined. Miscellaneous macromolecular architectures, including block copolymers, stars and star block copolymers, were derived by this chemistry.

KW - Block copolymers

KW - Controlled radical polymerization

KW - N-butyl acrylate

KW - N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide

KW - Star polymers

KW - Styrene

UR - http://www.scopus.com/inward/record.url?scp=0043198762&partnerID=8YFLogxK

U2 - 10.14314/polimery.2003.499

DO - 10.14314/polimery.2003.499

M3 - Article

AN - SCOPUS:0043198762

SN - 0032-2725

VL - 48

SP - 499

EP - 504

JO - Polimery/Polymers

JF - Polimery/Polymers

IS - 7-8

ER -

Controlled radical polymerization in the presence of β-phosphonylated nitroxide - Kinetics, mechanism and macromolecular architecture

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this