Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand

M. O. Barsukova; D. G. Samsonenko; T. V. Goncharova; A. S. Potapov; S. A. Sapchenko; D. N. Dybtsev; V. P. Fedin

doi:10.1007/s11172-016-1677-4

Coordination polymers with adjustable dimensionality based on Cu^II and bis-imidazolyl bridging ligand

M. O. Barsukova, D. G. Samsonenko, T. V. Goncharova, A. S. Potapov, S. A. Sapchenko, D. N. Dybtsev, V. P. Fedin^*

^*Corresponding author for this work

Advanced Membranes and Porous Materials Center

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl₂] (1) and [Cu(bImB)₂Cl₂] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

Original language	English (US)
Pages (from-to)	2914-2919
Number of pages	6
Journal	Russian Chemical Bulletin
Volume	65
Issue number	12
DOIs	https://doi.org/10.1007/s11172-016-1677-4
State	Published - Dec 1 2016

Keywords

bis(imidazolyl)alkanes
coordination polymer
copper
X-ray diffraction

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/s11172-016-1677-4

Cite this

@article{a982b1544a47428083754d8e6a8ef2be,

title = "Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand",

abstract = "1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.",

keywords = "bis(imidazolyl)alkanes, coordination polymer, copper, X-ray diffraction",

author = "Barsukova, {M. O.} and Samsonenko, {D. G.} and Goncharova, {T. V.} and Potapov, {A. S.} and Sapchenko, {S. A.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

note = "Publisher Copyright: {\textcopyright} 2016, Springer Science+Business Media New York.",

year = "2016",

month = dec,

day = "1",

doi = "10.1007/s11172-016-1677-4",

language = "English (US)",

volume = "65",

pages = "2914--2919",

journal = "Russian Chemical Bulletin",

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T1 - Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand

AU - Barsukova, M. O.

AU - Samsonenko, D. G.

AU - Goncharova, T. V.

AU - Potapov, A. S.

AU - Sapchenko, S. A.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - 1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

AB - 1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.

KW - bis(imidazolyl)alkanes

KW - coordination polymer

KW - copper

KW - X-ray diffraction

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U2 - 10.1007/s11172-016-1677-4

DO - 10.1007/s11172-016-1677-4

M3 - Article

AN - SCOPUS:85019754128

SN - 1066-5285

VL - 65

SP - 2914

EP - 2919

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 12

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